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Explain synergic effect in the formation...

Explain synergic effect in the formation of metal carbonyls. 

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Metal - carbon had both o and a bond between them
`M-C sigma` bond by donating electron pair from c to metal
`M-C pi` bond by donating electron pair from filled d of metal to it. of carbon
Thus `M-C` bond is strengthened. This is synergic effect
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