Home
Class 12
CHEMISTRY
Calculate the e.m.f. of the cell in whic...

Calculate the e.m.f. of the cell in which the following reaction takes place.
`Ni_((s)) + 2Ag_((0.002M))^(+) to Ni_((0.160M))^(2+) + 2Ag_((s)) , "Given " E_("cell")^@ = 1.05 V `

Text Solution

Verified by Experts

`E_("cell")=E_("cell")^(@)-(0.0591)/(n)log""([N_(i)^(2+)])/([Ag^(+)]^(2))`
`=1.05-(0.0591)/(2)log""(0.160)/((0.002)^(2))`
`=1.05-0.2955log0.44xx10^(+6)`
`=1.05-0.2955log(4xx10^(4))`
`=1.05-0.02955(0.6021+4)-0.914V`
Promotional Banner

Topper's Solved these Questions

  • SUPPLEMENTARY EXAM QUESTION PAPER JULY - 2018

    SUNSTAR PUBLICATION|Exercise PART - C|11 Videos
  • K-CET-CHEMISTRY-2019

    SUNSTAR PUBLICATION|Exercise Question|60 Videos
  • SUPPLEMENTARY EXAM QUESTION PAPER JULY - 2015

    SUNSTAR PUBLICATION|Exercise PART - D|30 Videos

Similar Questions

Explore conceptually related problems

(a) Calculate the emf of the cell in which the following reaction takes place Ni(S) + 2Ag^(+)(0.002M) rarr Ni^(2+)(0.160M) + 2Ag(S) Given that E_(cell)^(circ)= 1.05V (b) A galvanic cell after use is recharged by passing current through it. What type of cell is it? Give an example.

Represent the cell in which the following reaction takes place Mg(s)+2Ag^(+)(0.001M) to Mg^(2+)(0.130)+2Ag(s) Calculate E_("cell")" if "E_("cell")^(0)=3.17V .

For a given data : E_(Mg^(2+) // Mg)^(@) = -2.37 V , E_(Cu^(2+)// Cu)^(@) = + 0.34 V Calculate the emf of the cell in which the following reaction takes place . underset((0.0001 M)) ( Mg_((s))) + Cu_((aq))^(2+) underset((0.001M)) to Mg_((aq))^(2+) + Cu_((s))

a) Calculate the e.m.f. of the cell represented below: Ni_((s))|Ni_(0.1M)^(2+)||Ag_(0.01M)^(+)|Ag_((s))" at 298 Given, "E_("cell")^(@)=1.05V ,

b) Calculate Delta_(r)G^(@) for the following reaction: Fe_((aq))^(+2)+Ag_((aq))^(+)rarr Fe_((aq))^(+3)+Ag(s)." "("Given : "E_("cell")^(@)=+0.03V, F=96500C) .

SUNSTAR PUBLICATION-SUPPLEMENTARY EXAM QUESTION PAPER JULY - 2018-PART - D
  1. 5.8 g of non - volatile, non - electrolyte solute was dissolved in 100...

    Text Solution

    |

  2. Mention any two differences between ideal and non-ideal solutions.

    Text Solution

    |

  3. Calculate the e.m.f. of the cell in which the following reaction takes...

    Text Solution

    |

  4. State the Faraday's first law of electrolysis. How many Faraday of ele...

    Text Solution

    |

  5. Derive an integrated rate equation for the rate constant of a zero ord...

    Text Solution

    |

  6. Draw a graph of potential energy V/S reaction co - ordinates showing t...

    Text Solution

    |

  7. Write any two characteristics of chemical adsorption.

    Text Solution

    |

  8. What is Brownain movement ? What is the cause for it ?

    Text Solution

    |

  9. What is homogenous catalysis? Give an example.

    Text Solution

    |

  10. Write equations for the steps in S(N)1 mechanism of conversion of tert...

    Text Solution

    |

  11. Explain Wurtz-Fitting reaction with equation.

    Text Solution

    |

  12. CH(3)Cl + NaI overset("Dry acetone")rarr CH(3)I + NaCl. Name the above...

    Text Solution

    |

  13. Write the mechanism of acid catalysed dehydration of ethanol to ethene...

    Text Solution

    |

  14. How does anisole react with bromine in ethanoic acid ? Give equation.

    Text Solution

    |

  15. Complete the following equations : (i) (iii) CH(3)COONa overset(N...

    Text Solution

    |

  16. Explain esterification reaction with an example.

    Text Solution

    |

  17. How is methylamine prepared by Hoffmann bromamide degradation reaction...

    Text Solution

    |

  18. How is aniline converted to Benzene diazonium chloride ? Give equation...

    Text Solution

    |

  19. b) What is Hinsberg's reagent? Between CH(3)NH(2) and C(6)H(5)NH(2) wh...

    Text Solution

    |

  20. Write Haworth structure for maltose.

    Text Solution

    |