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Show mechanistic path way of the reaction tertiary butyl bromide is treated with aqueous KOH solution. Convert Iodobenzene from benzene.

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Compound 'A' with molecular formula C_(4)H_(9)Br is treated with aq.KOH solution. The rate of this reaction depends upon the concentration of the compound 'A' only. When another optically active isomer 'B' of this compound was treated with aq. KOH solution, the rate of reaction was found to be dependent on concentration of compound and KOH both. (i) Write down the structural formula of both compounds 'A' and 'B'. (ii) Out of these two compounds, which one will be converted to the product with inverted configuration.

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Explain: (1) A mixture of ether and water can be separated by simple distillation. (2) Water present in rectified spirit can be removed by azeotropic distillation. (3) Benzoic acid can be extarced from its aqueous solution using benzene. (4) Sugar containing NaCI as impurity can be purified by crystallisation using ethanol but not water. '

This question has statement I and Statement II . Of the four choices given after the statements, choose the one that best describes the two Statements. Statement-I:SN2 reaction of an optically active alkyl halide with and aqueous solution of KOH always gives an alcohol with opposite sign of rotation. Statement-II:SN2 reactions always proceed with inversion of configuration

UNITED BOOK HOUSE-SET-15-EXERCISE
  1. Complete the followign reaction. XeF6 + H2O rarr

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  2. Write General electronic configuraiton for group 18-f-block element. H...

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  3. Show mechanistic path way of the reaction tertiary butyl bromide is tr...

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  4. Identify A,B,C,D,E,F in the reaction given below:

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  5. An organic compound A (C3H5N) when heated with concentrated NaOH, NH3 ...

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  6. Arrange the following acid as per their increasing strength - State re...

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  7. State the arrowhead equation for the reaction given below: Propanone i...

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  8. State the product:- CH3- CH = CH - CHO + NaBH4 rarr?

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  9. State the product:- CH3CHO+SeO2 rarr?

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  10. State the product:- C6H5COOH + Br2 overset(FeBr3) rarr ?

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  11. State the product:- CH3COOH + CH2N2 overset (Ether)rarr ?

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  12. State the product:- (CH3)2 CO + CH3MgBr overset(H2O) rarr?

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  13. What do you mean by isoelectric point of an amino acid being 9.5? Name...

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  14. Prove that for any first order reaction time to complete the reaction ...

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  15. State the postulates of reaciton rate. What is temperature co-efficien...

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  16. The specific reaction-rate constant for a decomposition reaction at 15...

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  17. Mention two differences between bleaching action of SO2 and CI2.

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  18. Which one has highest Catenation property between N2 and Phosphorus an...

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  19. Which solutions can be reduced by phosphine?

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  20. Give one example each for the the folloiwng: Hunsdicker reaction.

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