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Anodic oxidation of ammonium hydrogen su...

Anodic oxidation of ammonium hydrogen sulphate produces ammonium persulphate.
`NH_(4) HSO_(4) rarr NH_(4)SO_(4)^(-) + H^(+)`
`2NH_(4) SO_(4)^(-) rarr (NH_(4))_(2) S_(2) O_(8) + 2e^(-)` (Anodic oxidation)
`2H^(+) + 2e^(-) rarr H_(2)` (Cathodic reduction)
Hydrolysis of ammonium persulphate forms `H_(2)O_(2)`
`(NH_(2))_(2) S_(2)O_(8) + 2H_(2)O rarr 2NH_(4) HSO_(4) + H_(2)O_(2)`
Current efficiency in electrolytic process is 60%. Calculate the amount of current required to produce 85 g of `H_(2)O_(2)` per hour: Hydrolysis reaction shows 100% yield.

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H_(2)O_(2) can be produced by the ammonium hydrogen sulphate. Reactions occuring in electrolytic cell, NH_(4)HSO_(4)rarrNH_(4)^(-)+2e^(-) (Anode) 2SO_(4)^(2-)rarrS_(2)O_(8)^(2-)+2e^(-) 2H^(+)+2e^(-)rarrH_(2) (Cathode) Hydrolysis of ammonium persulphate: (NH_(4))_(2)S_(2)O_(8)+2H_(2)Orarr2NH_(4)HSO_(4)+H_(2)O_(2) Assume 100% yield of hydrolysis reaction. What is the current efficiency when 100 Amp current is passed for 965 seconds in order to produce 17 gm of H_(2)O_(2) .

NH_(3) and H_(2)O form NH_(4)OH by

H_(2)O_(2) can be produced by the ammonium hydrogen sulphate. Reactions occuring in electrolytic cell, NH_(4)HSO_(4)rarrNH_(4)^(-)+2e^(-) (Anode) 2SO_(4)^(2-)rarrS_(2)O_(8)^(2-)+2e^(-) 2H^(+)+2e^(-)rarrH_(2) (Cathode) Hydrolysis of ammonium persulphate: (NH_(4))_(2)S_(2)O_(8)+2H_(2)Orarr2NH_(4)HSO_(4)+H_(2)O_(2) Assume 100% yield of hydrolysis reaction. What volume of hydrogen gas at 1 atm and 273 K will be produced in cathode in previous question?

H_(2)O_(2) can be produced by the ammonium hydrogen sulphate. Reactions occuring in electrolytic cell, NH_(4)HSO_(4)rarrNH_(4)^(-)+2e^(-) (Anode) 2SO_(4)^(2-)rarrS_(2)O_(8)^(2-)+2e^(-) 2H^(+)+2e^(-)rarrH_(2) (Cathode) Hydrolysis of ammonium persulphate: (NH_(4))_(2)S_(2)O_(8)+2H_(2)Orarr2NH_(4)HSO_(4)+H_(2)O_(2) Assume 100% yield of hydrolysis reaction. How many "mole"s of electrons are to be passed in order to produce enough H_(2)O_(2) which when reacted with excess of KI then liberated iodine required 100 mL of centimolar hypo solution.

Calculate the number of H atoms in 39.6g of ammonium sulphate, (NH_(4))_(2) SO_(4) .

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