Home
Class 12
CHEMISTRY
Calculate the equilibrium constant for t...

Calculate the equilibrium constant for the following reaction at `25^@C` .
`Ag^(+)(aq) + Fe^(2+)(aq) to Ag(s) + Fe^(3+)(aq)`
The standard emf of the corresponding voltaic cell is 0.03 V.

Text Solution

AI Generated Solution

To calculate the equilibrium constant (K) for the reaction: \[ \text{Ag}^+(aq) + \text{Fe}^{2+}(aq) \rightleftharpoons \text{Ag}(s) + \text{Fe}^{3+}(aq) \] at \( 25^\circ C \) given that the standard emf (\( E^\circ \)) of the corresponding voltaic cell is \( 0.03 \, V \), we can follow these steps: ### Step 1: Identify the number of electrons transferred (N) In the given reaction, silver ion (\( \text{Ag}^+ \)) is reduced to solid silver (\( \text{Ag} \)), and iron ion (\( \text{Fe}^{2+} \)) is oxidized to iron ion (\( \text{Fe}^{3+} \)). The transfer of electrons can be represented as follows: ...
Promotional Banner

Topper's Solved these Questions

  • MISCELLANEOUS OBJECTIVE QUESTIONS

    RC MUKHERJEE|Exercise MCQ|277 Videos
  • MOLECULAR WEIGHT

    RC MUKHERJEE|Exercise PROBLEMS |12 Videos

Similar Questions

Explore conceptually related problems

Calculate equilibrium constant for the reaction at 25^(@)C Cu(s)+2Ag^(+)(aq) hArr Cu^(2+)(aq)+2Ag(s) E^(@) value of the cell is 0.46 " V " .

Calculate the equilibrium constant of the reaction : Cu(s)+2Ag(aq) hArrCu^(2+)(aq) +2Ag(s) E^(c-)._(cell)=0.46V

Calculating the thermodynamic equilibrium constant from the cell emf : The standard emf for the following galvanic cell is 0.46 V Cu(s)|Cu^(2+)(aq.)||Ag^(+)(aq.)|Ag(s) Calculate the equilibrium cosntant K_(C) for the reaction Cu(s)+2Ag^(+)(aq.)hArr Cu^(2+)(aq.)+2Ag(s) Strategy : Substitute the standard emf into the Equation (3.9) realting this quantity to the thermodynatmic equilibrium constant, K_(eq.). Solve K_(eq.). Note that K_(eq.). = K_(C^(.))

At 25^(@)C equilibrium constant for the reaction Ni_((s))+2Ag_((aq))^(+) too Ni_((aq))^(++)+2Ag_((s)) is 2 xx 10^(35) , then emf of the cell is

The equilibrium constant of the reaction : Zn(s)+2Ag^(+)(aq)toZn(aq)+2Ag(s),E^(@)=1.50V at 298 K is

The equilibrium constant (K) for the reaction Cu(s)+2Ag^(+) (aq) rarr Cu^(2+) (aq)+2Ag(s) , will be [Given, E_(cell)^(@)=0.46 V ]

The expression for equilibrium constant, K_(c) for the following reaction is Fe_((aq))^(3+)+3OH_((aq))^(-)hArrFe(OH)_(3(s))

RC MUKHERJEE-MISCELLANEOUS PROBLEMS FOR REVISION-SUBJECTIVE TYPE QUESTIONS
  1. An alloy of iron (54.7%), nickel (45.0%) and manganese (0.3%) has a de...

    Text Solution

    |

  2. (a) Calculate the equilibrium constant for the following reaction at 2...

    Text Solution

    |

  3. Calculate the equilibrium constant for the following reaction at 25^@C...

    Text Solution

    |

  4. When equal volumes of 1.0 M solutions of Ag^+ and Fe^(2+) are mixe...

    Text Solution

    |

  5. The thermochemical equation for the dissociation of hydrogen gas into ...

    Text Solution

    |

  6. A mixture of N2 and Ne contains equal moles of each gas and has a tot...

    Text Solution

    |

  7. Calculate the hydronium-ion concentration and the sulphide ion concent...

    Text Solution

    |

  8. Calculate [SO4^(2-) ] in 0.15 M H2SO4 solution if the first step of ...

    Text Solution

    |

  9. Under standard conditions for all concentrations, the following reacti...

    Text Solution

    |

  10. An electrode is prepared by dipping an Ag strip into a solution satura...

    Text Solution

    |

  11. An ideal gas with density of 3.0 g/L has pressure of 675 mmHg at 25^@C...

    Text Solution

    |

  12. Under standard conditions for all concentrations, the following reacti...

    Text Solution

    |

  13. How many moles of NH, must be added to 1 litre of 0.75 M AgNO3 in ord...

    Text Solution

    |

  14. What fraction of a mole of iron metal will be produced by passage of 4...

    Text Solution

    |

  15. Metallic Mg has a hexagonal close-packed structure and a density of 1....

    Text Solution

    |

  16. A solution is 0.10 M in Na2 SO4 . When 50 mL of 0.1 M Ba(NO3) , is add...

    Text Solution

    |

  17. A metallic crystal cystallizes into a lattice containing a sequence of...

    Text Solution

    |

  18. A sample of ""^14CO2 was to be mixed with ordinary CO2 for biologic...

    Text Solution

    |

  19. Which state of the triply ionised beryllium, Be^(3+) has the same rad...

    Text Solution

    |

  20. At what temperature would the average translational kinetic energy of ...

    Text Solution

    |