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In certain areas where coal is cheap, ar...

In certain areas where coal is cheap, artificial gas is produced for household use by the 'water gas' reaction
`C(s) + H_2O(g) overset(600^@C)(to) H_2(g) + CO(g)`
Assuming that coke is 100% carbon, calculate the maximum heat obtainable at 298 K from the combustion of 1.0 kg of coke and compare this value to the maximum heat obtainable at 298 K from burning the water gas produced from 1.0 kg of coke. Heat of combustion of C, `H_2` and CO are -94.1, -68.4 and -68.0 kcal/mole respectively.

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To solve the problem, we will follow these steps: ### Step 1: Calculate the heat obtainable from the combustion of 1.0 kg of coke (carbon). 1. **Determine the number of moles of carbon in 1.0 kg of coke:** - Molar mass of carbon (C) = 12 g/mol - 1.0 kg = 1000 g - Number of moles of carbon = \( \frac{1000 \text{ g}}{12 \text{ g/mol}} = 83.33 \text{ moles} \) ...
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In certan areas where coal is cheap, artificial gas is produced for household use by the ''water gas'' raction C(s) +H_(2)O(g) underset(600^(@)C)rarr H_(2)(g) +CO(g) Assuming that coke is 100% carbon, calculate the maximum heat obtainable at 298K from the combustion of 1kg of coke, and compare this value to the maximum heat obtainable at 298K from burning the water was produced from 1.00 kg of coke. GIven: Delta_(f)H^(Theta), H_(2)O(l) =- 68.32 kcal//mol Delta_(f)H^(Theta),CO_(2) (g) =- 94.05 kcal//mol Delta_(f)H^(Theta),CO(g) =- 26.42 kcal//mol

The ratio of heat liberated at 298 K from the combustion of one kg of coke and by burning, water gas obtained from 1 kg of coke is (assume coke to be 100% carbon, enthalpies of combustion of C, CO and H_(2) as 393.5 kJ, 285 kJ, 285 kJ respectively all at 298 K).

Calculate the standard heat of formation of C_(10)H_(8) (naphthalene) if standard heat of combustion of nephathalene is -123.0 kcal at 298K and standard heats of formation of CO_(2)(g) and H_(2)O(l) are -94.0 kcal and -68.4 kcal respectively.

Calculate the heat of combustion of 1 mole of C_(2)H_(4)(g) to form CO_(2)(g) and H_(2)O(g) at 398K and 1 atmosphere, given that the heats of formation of CO_(2)(g),H_(2)O(g) and C_(2)H_(4)(g) are -94.1,-57.8 and +12.5kcal" "mol^(-1) respectively.

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