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Standard potentials (E°) for some half-r...

Standard potentials (E°) for some half-reactions are given below:
`Sn^(4+) + 2e rightarrow Sn^(2+) , E^(@) = + 0.15V`
`2Hg^(2+) + 2e rightarrow Hg_(2)^(2+) , E^(@) = 0.92 V`
`pbo_(2) + 4H^(+) + 2e rightarrow pb^(2+)+ 2H_(2)O , E^(@) = + 1.45 V`
Based on the above , Which one of the following statement is correct?

A

`Sn^(4+)` is a stronger oxidising agent than `Pb^(4+)`.

B

`Sn^(2+)` is a stronger reducing agnet than `Hg_(2)^(2+)`.

C

`Hg^(2+)` is a stronger oxidising agent than `Pb^(4+)`.

D

`Pb^(2+)` is a stronger reducing agnet than `Sn^(2+)`.

Text Solution

Verified by Experts

The correct Answer is:
D
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The standard oxidation potential, E^(@) , for the reactions are given as: Zn rightarrow Zn^(2+) + 2e^(-) , E^(@) = +0.76V Fe rightarrow Fe^(2+) + 2e^(-) , E^(@) = +0.41V The emf for the cell : Fe^(2+) + Zn rightarrow Zn^(2+) + Fe

The standard oxidation potentials, , for the half reactions are as follows : Zn rightarrow Zn^(2+) + 2e^(-) , E^(@) = +0.76V Fe rightarrow Fe^(2+)+ 2e^(-), E^(@) = + 0.41 V The EMF for the cell reaction, Fe^(2+) + Zn rightarrow Zn^(2+) + Fe

The standard reduction potential E^(@) for the half reactions are as : E^(@) Znrightarrow Zn^2+),E^(@) = +0.76V Fe rightarrow Fe^(2+)+ 2e^(-), E^(@) = 0.41V , The emf for the cell reaction, Fe^(2+)+ZnrightarrowZn^(2+) + Fe is ,

MnO_(4)^(-) + 8H^(+) + 5e^(-) rightarrow Mn^(2+) + 4H_(2)O , E^(@) = 1.51V MnO_(2) + 4H^(+) + 2e^(-) righarrow Mn^(2+) + 2H_(2)O E^(@) = 1.23V E_(MnO_(4)^(-)|MnO_(2)

Cu^(+) + e^(-) rightarrow Cu , E^(@) = x1volt , Cu^(2+) + 2e^(-) rightarrow Cu , E^(@) = x_(2) volt, then for Cu^(2+) + e^(-) rightarrow Cu^(+), E^(@) (volt) will be :

Given : E^(@) (Cu^(2+//Cu) = 0.337V and E^(@) (Sn^(2+//Sn) = -0.136V . Which of the following statements is correct?

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