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x and y moles/litre of A and B respectiv...

x and y moles/litre of A and B respectively were allowed to react `A+2BhArr1/2C`. At equilibrium, the concentrations of A, B and C were found to be 4, 2 and 2 moles/litre respectively, x and y are

A

6 & 4

B

8 & 10

C

6 & 10

D

8 & 4

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the given chemical reaction and the information provided about the concentrations at equilibrium. ### Step-by-Step Solution: 1. **Write the Balanced Chemical Equation:** The reaction given is: \[ A + 2B \rightleftharpoons \frac{1}{2}C \] 2. **Define Initial Concentrations:** Let the initial concentrations of A and B be \(x\) moles/litre and \(y\) moles/litre respectively. 3. **Define Change in Concentrations:** Let \( \alpha \) be the amount of A that reacts at equilibrium. According to the stoichiometry of the reaction: - For A: \( \text{Change} = -\alpha \) - For B: \( \text{Change} = -2\alpha \) - For C: \( \text{Change} = +\frac{\alpha}{2} \) 4. **Write Equilibrium Concentrations:** At equilibrium, the concentrations can be expressed as: - Concentration of A: \( [A] = x - \alpha \) - Concentration of B: \( [B] = y - 2\alpha \) - Concentration of C: \( [C] = \frac{\alpha}{2} \) 5. **Set Up Equations Based on Given Equilibrium Concentrations:** We know from the problem that at equilibrium: - \( [A] = 4 \) moles/litre - \( [B] = 2 \) moles/litre - \( [C] = 2 \) moles/litre This gives us the following equations: \[ x - \alpha = 4 \quad \text{(1)} \] \[ y - 2\alpha = 2 \quad \text{(2)} \] \[ \frac{\alpha}{2} = 2 \quad \text{(3)} \] 6. **Solve Equation (3) for \( \alpha \):** From equation (3): \[ \frac{\alpha}{2} = 2 \implies \alpha = 4 \] 7. **Substitute \( \alpha \) into Equations (1) and (2):** Substitute \( \alpha = 4 \) into equation (1): \[ x - 4 = 4 \implies x = 8 \] Substitute \( \alpha = 4 \) into equation (2): \[ y - 2(4) = 2 \implies y - 8 = 2 \implies y = 10 \] 8. **Final Values:** Thus, the values of \(x\) and \(y\) are: \[ x = 8 \quad \text{and} \quad y = 10 \] ### Conclusion: The final answer is: - \( x = 8 \) - \( y = 10 \)
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