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The reaction A+2Bto product, is first or...

The reaction `A+2Bto` product, is first order in A and second order in B. If `t_(1//2)` w.r.t. A is same as the `t_(1//2)` of the reaction.

A

`[A]_("Initial")gt[B]_("Initial")`

B

`[A]_("Initial")=[B]_("Initial")`

C

A is the limiting reactant

D

B is the limiting reactant

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AI Generated Solution

The correct Answer is:
To solve the given problem, we need to analyze the reaction and the information provided about its order and half-life. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ A + 2B \rightarrow \text{Products} \] It is stated that this reaction is first order in A and second order in B. 2. **Order of Reaction**: - The overall order of the reaction can be calculated by adding the orders with respect to each reactant: - Order with respect to A = 1 (first order) - Order with respect to B = 2 (second order) - Therefore, the overall order of the reaction is: \[ \text{Overall Order} = 1 + 2 = 3 \] 3. **Half-Life of the Reaction**: The half-life (\(t_{1/2}\)) of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. For a reaction that is first order in A and second order in B, the half-life expressions are different: - For a first-order reaction, the half-life is given by: \[ t_{1/2} = \frac{0.693}{k[A]_0} \] - For a second-order reaction, the half-life is given by: \[ t_{1/2} = \frac{1}{k[B]_0} \] 4. **Condition Given in the Question**: The question states that the half-life with respect to A is the same as the half-life of the reaction. This implies: \[ t_{1/2} \text{ (with respect to A)} = t_{1/2} \text{ (overall reaction)} \] 5. **Implications of the Condition**: For the half-lives to be equal, it suggests that the concentration of A is very low compared to B. This means that A is the limiting reactant. As A is consumed, the reaction stops, and thus the rate of reaction is primarily dependent on the concentration of B. 6. **Conclusion**: Therefore, the condition where the half-life of A equals the half-life of the overall reaction occurs when A is the limiting reagent. This leads us to conclude that the correct option is that A is in excess or limiting. ### Final Answer: The correct option is that A is a limiting reactant.
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