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Identify the anion present in the follow...

Identify the anion present in the following compounds:
i] Compound X on heating with copper turnings & conc. sulphuric acid liberates a reddish brown gas.
ii] When a solution of compound Y is treated with silver nitrate solution a white precipitate is obtained which is soluble in excess of ammonium hydroxide solution.
iii] Compound Z which on reacting with dilute sulphuric acid liberates a gas which turns lime water milky, but the gas has no effect on acidified potassium dichromate solution.
iv] Compound L on reacting with barium chloride solution gives a white precipitate insoluble in dilute hydrochloric acid or dilute nitric acid.

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