Home
Class 12
CHEMISTRY
Calculate the cell potential for the fol...

Calculate the cell potential for the following galvanic cell:
The first electrode consists of `Fe^(3+)|Fe^(2+)` complete in which `[Fe^(3+)]=1M` and `[Fe^(2+)]=[0.1M]`
The second electrode consists of `MnO_4(-)|Mn^(2+)` couple in acidic solution in which
`[MnO_4^-]=1times 10^-2 M, [Mn^(2+)]=1 times 10^-4 M and [H^+]=1 times 10^-3 M`
`[E_(Fe^(3+),Fe^(2+))^@=0.771V, E_(MnO_4^-, Mn^(2+))^@=1.51V)`

Text Solution

Verified by Experts

0.42V
Promotional Banner

Topper's Solved these Questions

  • ELECTROMOTIVE FORCE

    BODY BOOKS PUBLICATION|Exercise EXERCISE |25 Videos
  • ELECTROMOTIVE FORCE

    BODY BOOKS PUBLICATION|Exercise EXERCISE |25 Videos
  • ELECTROCHEMISTRY

    BODY BOOKS PUBLICATION|Exercise EXAMPLES|134 Videos
  • General Principles and Processes of Isolation of Elements

    BODY BOOKS PUBLICATION|Exercise Example|108 Videos

Similar Questions

Explore conceptually related problems

Calculate the reduction potential for the following half cells at 25^@C Pt|Fe^(2+) (0.1M)-Fe^(3+) (0.01M), E_(Fe^(3+),Fe^(2+))^@=+0.77V

Calculate the reduction potential for the following half cells at 25^@C Mg|Mg^(2+) (1 times 10^-4 M), E_(Mg,Mg^(2+))^@=+2.36V

Derive expression to calculate emf (reduction) of the following half cells at 25^@C Fe^(3+)|Fe^(2+) (Pt)

Calculate the reduction potential for the following half cells at 25^@C Cl_2|Cl^(-)(2 times 10^-5 M), E_(Cl_2,Cl^-)^@=+1.36V

What is the standard electrode potential for the electrode, MnO_4^-//MnO_2 in an acid solution? E_(MnO_4^-,Mn^(2+))^@=1.51 V, E_(MnO_2,Mn^(2+))^@=1.23V

Calculate the emf of the following cells, find their cells reactions using E^@ values from the table? Pt|Fe^(2+) (1M), Fe^(3+) (0.1M) ||Cl^(-) (0.001M) |AgCl|Ag In each case, is the reaction as written spontaneous or not?

E^@ for the reaction Fe+Zn^(2+)=Zn+Fe^(2+) is -0.35 V. The given cell reaction is

Calculate the electrode potential of copper electrode in a 0.1 M copper sulphate solution at 25^(@) C. (E^(@)(Cu^(2+)|Cu) = 0.34V) .

How much is the oxidising power of the MnO_4^(-) (1M)|Mn^(2+) (1M) couple decreased if the H^+ concentration is decreased from 1M to 10^-4 M at 25^@C

Which of the following element has maximum first ionisation potential? 1)V 2)Ti 3)Cr 4)Mn

BODY BOOKS PUBLICATION-ELECTROMOTIVE FORCE -PROBLEMS
  1. Calculate the emf of the following cells, find their cells reactions u...

    Text Solution

    |

  2. Calculate the emf of the following cells, find their cells reactions u...

    Text Solution

    |

  3. Neglecting the liquid junction potential, calculate the emf of the fol...

    Text Solution

    |

  4. The emf of the cell, (Pt) H2|H^+ (c=unknown) ||KCN soln. |HgCl2|Hg i...

    Text Solution

    |

  5. Calculate the cell potential for the following galvanic cell: The f...

    Text Solution

    |

  6. Find the equilibrium constant at 25^@C for the reaction, Hg2(NO3)2+2...

    Text Solution

    |

  7. Calculate the potential of a silver electrode in a saturated solution ...

    Text Solution

    |

  8. Calculate the potential of a cell in which hydrogen electrode is immer...

    Text Solution

    |

  9. A galvanic cell is constructed of two hydrogen electrodes, one immerse...

    Text Solution

    |

  10. Using the electrochemical series table, explain why Cu (I) sulphate do...

    Text Solution

    |

  11. For the cell (Pt) H2 (1atm) |H^+ (pH unknown) ||H^+6 (pH=1)|H2 (1atm...

    Text Solution

    |

  12. Write the cell reaction and calculate the potential of the cell, Cl2...

    Text Solution

    |

  13. The emf of a galvanic cell composed of two hydrogen electrodes is 272m...

    Text Solution

    |

  14. Calculate the standard emf, standard free energy charge and equilibriu...

    Text Solution

    |

  15. What must be the pressure of the fluorine gas to produce a reduction m...

    Text Solution

    |

  16. Show by calculation that E^@=-1.662V for the reduction of Al^(3+) to A...

    Text Solution

    |

  17. Show by calculation that E^@=-1.662V for the reduction of Al^(3+) to A...

    Text Solution

    |

  18. If in a galvanic cell say, Daniel cell, an inert platinum is used inst...

    Text Solution

    |

  19. Does the physical size of a galvanic cell govern the potential that it...

    Text Solution

    |

  20. Consider the electrochemical cell represented by Mg|Mg^(2+) ||Fe^(3+...

    Text Solution

    |