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Back-bonding || Applications OF back bon...

Back-bonding || Applications OF back bonding || Bridge-bonding

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Bonding in metal carbonyls is represented by the end structures. overset(M-C-=O" "harr" "M=C=O)(I" "II) The contribution of I and II to the real structure depends upon the extent of pi- back bonding. Both sigma donation and pi- back bonding are synergitc. The filled orbitals CO overlap with vacant metal d orbitals which is called sigma donation. The filled metal d orbitals overlap with pi antibondig moleculat orbital of CO. which is called pi- back bonding . Which one of the following has the highest C-O bond length?

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Which will provide strong back bonding