Solution||Colligative properties||Problem on c.p & vantHOFf factor

Colligative property.

Colligative Properties: Osmotic pressure, Vant Hoff factor.

The colligative properties of solutions

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . van,t Hoff factor (i) for dimerisation of benzoic acid in water, assuming 30% degree of association is:

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . van't Hoff coefficient 'g' for 100% dissociated NaCl solution is:

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . The maximum elevation in b.pt. is noticed in :

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . The degree of dissociation of electrolyte A_(x)B_(y) is given by the relation:

Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i). What is observed molar mass of weak acid in soluton in above equation?

Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i). If equal volume of 0.01 M Ma OH is added in the solution of above weak acid solution then what will be new observed osmotic pressure at same temperature? Neglect the hydrolysis, dissociation of water and any volume concentration or expansion. Assume 10% dissociation of salt formed.

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . For 1M solution of HA having alpha gt 0.05 , the dissociation constant K_(a) in terms of van't Hoff factor (i) can be written as :