Synergic Bonding in NO/PCl3/H2 || Synergic Bonding in π-doner Ligands || List OF all imp π-doner/π* acceptor Ligand and their Representation || Hapticity

Ambidentate ligand || Flexidentate Ligands || Classical and Non-Classical Ligands || π-Donor and π-Acceptor Ligands || Oxidation Number

Two important physical evidences supporting the synergic bonding in non-classical complexes are bond lengths and vibrational spectra. Vibrational spectra is based on the fact that the compression and extension of a bond may be analogous to the behaviour of a spring and obeys Hook's law. overline(v)=(1)/(2pic)sqrt((k)/(mu))cm^(-1) where, k=force force constant of the bond which is directly proportional to bonnd strength of CO mu= reduced mass of ligand overline(v) =stretching frequency of the CO bond c=velocity of light Q. In which of the following ligand, sigma -bond order does not change during synergic bonding in their respective complexes:

Two important physical evidences supporting the synergic bonding in non-classical complexes are bond lengths and vibrational spectra. Vibrational spectra is based on the fact that the compression and extension of a bond may be analogous to the behaviour of a spring and obeys Hook's law. overline(v)=(1)/(2pic)sqrt((k)/(mu))cm^(-1) where, k=force force constant of the bond which is directly proportional to bonnd strength of CO mu= reduced mass of ligand overline(v) =stretching frequency of the CO bond c=velocity of light Q. In Mn_(2)(CO)_(10) carbonyl complex, the d-orbital of Mn-atom which can not be involved in synergic bonding betwee Mn and CO ligands:

Two important physical evidence support the synergic bonding in non-classical complexes-bond lengths and vibrational spectra. Vibrational spectra is based on the fact that the compression and extension of a bond may be analogous to the behaviour of spring and obeys Hooke's law. overset(-)v=(1)/(2pic) sqrt((K)/(mu))cm^(-1) Where, K=force constant of the bond which is directly proportional to bond strngth mu="reduced mass of ligand" overset(-)v="stretching frequency of the CO bond" C="velocity of light" In which of the following complex, stretching frquency for C-O bond is least as well as bond energy of M-C bond is highest ?