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During the electrolysis of molten lead b...

During the electrolysis of molten lead bromide , which of the following takes place ? Bromine is released at the cathode Lead is deposited at the anode Bromine ions gain electrons Lead is deposited at the cathode

A

Bromine is released at the cathode

B

Lead is deposited at the anode

C

Bromine ions gain electrons

D

Lead is deposited at the cathode

Text Solution

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The correct Answer is:
To solve the question regarding the electrolysis of molten lead bromide (PbBr2), we will analyze the processes occurring at both the cathode and the anode during the electrolysis. ### Step-by-Step Solution: 1. **Understanding Electrolysis**: Electrolysis involves the breakdown of an ionic compound into its elements using electricity. In this case, we are dealing with molten lead bromide (PbBr2). 2. **Identify the Electrodes**: In electrolysis, there are two electrodes: - **Cathode**: The negative electrode where reduction occurs (gain of electrons). - **Anode**: The positive electrode where oxidation occurs (loss of electrons). 3. **Determine the Ions Present**: In molten lead bromide, the ions present are: - Lead ions (Pb²⁺) - Bromide ions (Br⁻) 4. **Reactions at the Cathode**: - At the cathode, lead ions (Pb²⁺) will gain electrons (reduction) to form lead metal (Pb). - Reaction: \[ \text{Pb}^{2+} + 2e^- \rightarrow \text{Pb (s)} \] - Therefore, lead is deposited at the cathode. 5. **Reactions at the Anode**: - At the anode, bromide ions (Br⁻) will lose electrons (oxidation) to form bromine gas (Br₂). - Reaction: \[ 2\text{Br}^- \rightarrow \text{Br}_2 + 2e^- \] - Thus, bromine is released at the anode. 6. **Conclusion**: From the analysis, we can conclude: - Lead is deposited at the cathode. - Bromine is released at the anode. ### Final Answer: - **Lead is deposited at the cathode.** - **Bromine is released at the anode.**
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