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SnCl(2) gives a precipitate with a solut...

`SnCl_(2)` gives a precipitate with a solution of `HgCl_(2)`. In this process, `HgCl_(2)` is

A

reduced

B

oxidised

C

converted into a complex compound containing both Sn and Hg

D

converted into a chloro complex of Hg.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction between SnCl₂ and HgCl₂, we need to analyze the changes in oxidation states of the elements involved in the reaction. Here’s a step-by-step breakdown of the solution: ### Step 1: Write the balanced chemical equation The reaction between tin(II) chloride (SnCl₂) and mercury(II) chloride (HgCl₂) can be represented as follows: \[ \text{SnCl}_2 + \text{HgCl}_2 \rightarrow \text{SnCl}_4 + \text{Hg}_2\text{Cl}_2 \] ### Step 2: Determine the oxidation states Next, we need to determine the oxidation states of tin (Sn) and mercury (Hg) in the reactants and products. - In SnCl₂: - Chlorine (Cl) has an oxidation state of -1. - Let the oxidation state of Sn be \( x \). - The equation becomes: \( x + 2(-1) = 0 \) → \( x = +2 \). - Therefore, Sn in SnCl₂ is in the +2 oxidation state. - In HgCl₂: - Let the oxidation state of Hg be \( y \). - The equation becomes: \( y + 2(-1) = 0 \) → \( y = +2 \). - Therefore, Hg in HgCl₂ is also in the +2 oxidation state. - In SnCl₄: - Let the oxidation state of Sn be \( a \). - The equation becomes: \( a + 4(-1) = 0 \) → \( a = +4 \). - Therefore, Sn in SnCl₄ is in the +4 oxidation state. - In Hg₂Cl₂: - Let the oxidation state of Hg be \( b \). - The equation becomes: \( 2b + 2(-1) = 0 \) → \( 2b - 2 = 0 \) → \( b = +1 \). - Therefore, Hg in Hg₂Cl₂ is in the +1 oxidation state. ### Step 3: Identify oxidation and reduction Now, we can analyze the changes in oxidation states: - **Tin (Sn)**: Changes from +2 in SnCl₂ to +4 in SnCl₄. This is an increase in oxidation state, indicating that Sn is oxidized. - **Mercury (Hg)**: Changes from +2 in HgCl₂ to +1 in Hg₂Cl₂. This is a decrease in oxidation state, indicating that Hg is reduced. ### Step 4: Conclusion Since HgCl₂ undergoes a reduction process (gaining electrons), the correct answer to the question is that HgCl₂ is **reduced**. ### Final Answer In this process, HgCl₂ is **reduced**. ---
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ICSE-REDOX REACTIONS (OXIDATION AND REDUCTION)-OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS (Choose the correct option in the following questions:)
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  2. SnCl(2) gives a precipitate with a solution of HgCl(2). In this proces...

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  3. When a copper wire is placed in a solution of AgNO(3), the solution ac...

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  5. Which of the following is the strongest oxidising agent ?

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  6. Phosphorus has the oxidation state of +3 in

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  7. Oxygen has an oxidation state of +2 in

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  8. The most common oxidation state of an element is -2. The number of ele...

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  9. A metal ion M^(3+) after loss of three electrons in a reaction will ha...

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  10. The number of electrons to balance the equation NO(3)^(-)+4H^(+)+e^...

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  11. For the redox reaction, MnO4^- + C2 O4^(2-) + H^+ rarr Mn^(2+) + CO2 +...

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  12. Which one of the following reactions is not a redox reaction ?

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  13. Oxidation state of oxygen atom in potassium superoxide is

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  14. In the reaction C(3)H(6)(g)+nO(2)(g)toCO(2)(g)+H(2)O(l). The ratio o...

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  15. Phosphorus on reaction with NaOH produces PH(3) and NaH(2)PO(2). This ...

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  16. Which atom in the following reactions undergoes a change of oxidation ...

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  17. The ion acting as an oxidising agent in the reaction, Cr(2)O(7)^(2-)...

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  18. The stock notation for Mn(2)O(7) is

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  19. Calculate the oxidation number of the underlined element in the follow...

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  20. Which of the following is a redox decomposition reaction ?

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