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Which of the following is not a dispropo...

Which of the following is not a disproportionation reaction ?

A

`P_(4)(s)+3OH^(-)(aq)+3H_(2)O(l)toPH_(3)(g)+3H_(2)PO_(2)^(-)(aq)`

B

`2F_(2)(g)+2OH^(-)(aq)to2F^(-)(aq)+OF_(2)(g)+H_(2)O(l)`

C

`Cl_(2)(g)+2OH^(-)(aq)toClO^(-)(aq)+Cl^(-)(aq)+H_(2)O(l)`

D

`2H_(2)O_(2)(aq)to2H_(2)O(l)+O_(2)(g)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given reactions is not a disproportionation reaction, we first need to understand what a disproportionation reaction is. A disproportionation reaction occurs when a single species is simultaneously oxidized and reduced, resulting in two different products. ### Step-by-Step Solution: 1. **Identify the Reactions**: We are provided with four reactions. We need to analyze each reaction to see if the same species undergoes both oxidation and reduction. 2. **Define Oxidation and Reduction**: - **Oxidation**: Loss of electrons (increase in oxidation state). - **Reduction**: Gain of electrons (decrease in oxidation state). 3. **Analyze Each Reaction**: - **Reaction 1**: - **P4**: Oxidation state = 0. - **Products**: OH⁻, H₃PO₃, H₂P₂O₂. - **Phosphorus**: Changes from 0 to +1 (oxidation) and -3 (reduction). - **Conclusion**: This is a disproportionation reaction since phosphorus is both oxidized and reduced. - **Reaction 2**: - **Fluorine (F₂)**: Oxidation state = 0. - **Products**: F⁻, H₂O. - **Fluorine**: Changes from 0 to -1 (reduction) in both cases. - **Conclusion**: This is NOT a disproportionation reaction because fluorine does not undergo both oxidation and reduction. - **Reaction 3**: - **Cl₂**: Oxidation state = 0. - **Products**: Cl⁻, Cl⁺, H₂O. - **Chlorine**: Changes from 0 to +1 (oxidation) and -1 (reduction). - **Conclusion**: This is a disproportionation reaction since chlorine is both oxidized and reduced. - **Reaction 4**: - **H₂O₂**: Oxidation state of oxygen = -1. - **Products**: H₂O, O₂. - **Oxygen**: Changes from -1 to -2 (reduction) and -1 to 0 (oxidation). - **Conclusion**: This is a disproportionation reaction since oxygen is both oxidized and reduced. 4. **Final Conclusion**: The only reaction that is not a disproportionation reaction is **Reaction 2**. ### Answer: **The reaction that is not a disproportionation reaction is Reaction 2.** ---
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ICSE-REDOX REACTIONS (OXIDATION AND REDUCTION)-OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS (Choose the correct option in the following questions:)
  1. Calculate the oxidation number of the underlined element in the follow...

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  2. Which of the following is a redox decomposition reaction ?

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  3. Which of the following is not a disproportionation reaction ?

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  4. Balance the following equation by ion electron method in the acidic me...

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  5. Equivalent mass of C(2)O(4)^(2-) ion in the reaction, C(2)O(4)^(2-)t...

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  6. In the titration of FeSO(4) against KMnO(4) in acidic medium, one mole...

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  7. Calculate the oxidation number of the underlined atom in the following...

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  8. MnO(4)^(-) is a good oxidising agent in different mediums changing to ...

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  9. Oxidation number of Cl in CaOCl(2) (bleaching powder) is

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  10. The oxidation state of Cr in [Cr(NH(3))(4)Cl(2)]^(+) is

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  11. The oxidation state of chromium in the final product formed by the rea...

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  12. What products are expected from the disproportionation reaction of hyp...

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  13. Consider the following reaction, xMnO(4)^(-)+yC(2)O(4)^(2-)+zH^(+)to...

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  14. Oxidation states of P in H(4)P(2)O(5),H(4)P(2)O(6),H(4)P(2)O(7) respec...

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  15. A mixture of potassium chlorate, oxalic acid and sulphuric acid is hea...

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  16. In which of the following reactions H(2)O(2) acts as a reducing agent?...

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  17. The correct order of N-compounds in its decreasing order of oxidation ...

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  18. For the redox recation MnO(4)^(-)+C(2)O(4)^(2-)+H^(+)toMn^(2+)+CO(2)...

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  19. Which of the following reactions are disproportionation reactions ? ...

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  20. Arrange in the increasing order of oxidation state of nitrogen for fol...

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