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The oxidation state of Cr in [Cr(NH(3))(...

The oxidation state of Cr in `[Cr(NH_(3))_(4)Cl_(2)]^(+)` is

A

0

B

`+1`

C

`+2`

D

`+3`

Text Solution

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The correct Answer is:
To find the oxidation state of chromium (Cr) in the complex ion \([Cr(NH_3)_4Cl_2]^+\), we can follow these steps: ### Step 1: Identify the components of the complex The complex consists of: - 4 ammonia (NH₃) molecules - 2 chloride (Cl) ions - The overall charge of the complex is +1. ### Step 2: Assign oxidation states to the ligands - Ammonia (NH₃) is a neutral ligand, which means it has an oxidation state of 0. - Each chloride ion (Cl) has an oxidation state of -1. ### Step 3: Set up the equation for the oxidation state of chromium Let the oxidation state of chromium be \(X\). The contribution to the total charge from the ligands can be calculated as follows: - Contribution from 4 ammonia molecules: \(4 \times 0 = 0\) - Contribution from 2 chloride ions: \(2 \times (-1) = -2\) ### Step 4: Write the equation based on the total charge The total charge of the complex is +1. Therefore, we can set up the equation: \[ X + 0 + (-2) = +1 \] ### Step 5: Solve for \(X\) Now, we can simplify the equation: \[ X - 2 = +1 \] Adding 2 to both sides gives: \[ X = +1 + 2 \] \[ X = +3 \] ### Conclusion The oxidation state of chromium (Cr) in the complex \([Cr(NH_3)_4Cl_2]^+\) is +3. ### Final Answer The oxidation state of Cr in \([Cr(NH_3)_4Cl_2]^+\) is **+3**. ---
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ICSE-REDOX REACTIONS (OXIDATION AND REDUCTION)-OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS (Choose the correct option in the following questions:)
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  2. Which of the following is not a disproportionation reaction ?

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  3. Balance the following equation by ion electron method in the acidic me...

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  4. Equivalent mass of C(2)O(4)^(2-) ion in the reaction, C(2)O(4)^(2-)t...

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  6. Calculate the oxidation number of the underlined atom in the following...

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  8. Oxidation number of Cl in CaOCl(2) (bleaching powder) is

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  9. The oxidation state of Cr in [Cr(NH(3))(4)Cl(2)]^(+) is

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  10. The oxidation state of chromium in the final product formed by the rea...

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  11. What products are expected from the disproportionation reaction of hyp...

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  12. Consider the following reaction, xMnO(4)^(-)+yC(2)O(4)^(2-)+zH^(+)to...

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  13. Oxidation states of P in H(4)P(2)O(5),H(4)P(2)O(6),H(4)P(2)O(7) respec...

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  14. A mixture of potassium chlorate, oxalic acid and sulphuric acid is hea...

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  15. In which of the following reactions H(2)O(2) acts as a reducing agent?...

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  16. The correct order of N-compounds in its decreasing order of oxidation ...

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  17. For the redox recation MnO(4)^(-)+C(2)O(4)^(2-)+H^(+)toMn^(2+)+CO(2)...

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  18. Which of the following reactions are disproportionation reactions ? ...

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  20. In order to oxidise a mixture of one mole of each of FeC(2)O(4),Fe(2)...

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