Home
Class 11
CHEMISTRY
For the redox recation MnO(4)^(-)+C(2)...

For the redox recation
`MnO_(4)^(-)+C_(2)O_(4)^(2-)+H^(+)toMn^(2+)+CO_(2)+H_(2)O`
the correct coefficients of the reactants for the blalanced equation are

A

`{:(MnO_(4)^(-),C_(2)O_(4)^(2-),H^(+)),(2,16,5):}`

B

`{:(MnO_(4)^(-),C_(2)O_(4)^(2-),H^(+)),(2,5,16):}`

C

`{:(MnO_(4)^(-),C_(2)O_(4)^(2-),H^(+)),(16,5,2):}`

D

`{:(MnO_(4)^(-),C_(2)O_(4)^(2-),H^(+)),(5,16,2):}`

Text Solution

AI Generated Solution

The correct Answer is:
To balance the redox reaction given by: \[ \text{MnO}_4^{-} + \text{C}_2\text{O}_4^{2-} + \text{H}^{+} \rightarrow \text{Mn}^{2+} + \text{CO}_2 + \text{H}_2\text{O} \] we will use the oxidation number method. Here are the steps to find the correct coefficients of the reactants for the balanced equation: ### Step 1: Assign Oxidation States - For Mn in \(\text{MnO}_4^{-}\): Let the oxidation state be \(x\). The equation is \(x - 8 = -1\), so \(x = +7\). - For C in \(\text{C}_2\text{O}_4^{2-}\): Let the oxidation state be \(y\). The equation is \(2y - 8 = -2\), so \(2y = +6\) and \(y = +3\). - For Mn in \(\text{Mn}^{2+}\): The oxidation state is \(+2\). - For C in \(\text{CO}_2\): The oxidation state is \(z\). The equation is \(z - 4 = 0\), so \(z = +4\). ### Step 2: Identify Changes in Oxidation States - Mn changes from \(+7\) to \(+2\) (a decrease of \(5\)). - Each C changes from \(+3\) to \(+4\) (an increase of \(1\)). Since there are 2 C atoms in \(\text{C}_2\text{O}_4^{2-}\), the total increase is \(2\). ### Step 3: Balance the Changes in Oxidation States To balance the changes in oxidation states, we need to equalize the total decrease and increase: - Decrease: \(5\) (from Mn) - Increase: \(2\) (from C) To equalize, we multiply the oxidation half-reaction by \(2.5\) for the decrease and \(5\) for the increase. However, since we cannot have fractional coefficients, we will multiply the entire reaction by \(2\) to avoid fractions. ### Step 4: Write the Half-Reactions 1. **Reduction half-reaction**: \[ 2 \text{MnO}_4^{-} \rightarrow 2 \text{Mn}^{2+} \] 2. **Oxidation half-reaction**: \[ 5 \text{C}_2\text{O}_4^{2-} \rightarrow 10 \text{CO}_2 \] ### Step 5: Balance Oxygen and Hydrogen Now, we need to balance the oxygen and hydrogen atoms: - Total oxygen on the left: \(2 \times 4 + 5 \times 4 = 28\) - Total oxygen on the right: \(10 \times 2 + 8 \text{(from water)} = 20 + 8 = 28\) To balance the hydrogen, we add \(16 \text{H}^{+}\) to the left side: \[ 2 \text{MnO}_4^{-} + 5 \text{C}_2\text{O}_4^{2-} + 16 \text{H}^{+} \rightarrow 2 \text{Mn}^{2+} + 10 \text{CO}_2 + 8 \text{H}_2\text{O} \] ### Step 6: Final Balanced Equation The balanced equation is: \[ 2 \text{MnO}_4^{-} + 5 \text{C}_2\text{O}_4^{2-} + 16 \text{H}^{+} \rightarrow 2 \text{Mn}^{2+} + 10 \text{CO}_2 + 8 \text{H}_2\text{O} \] ### Step 7: Identify Coefficients The coefficients of the reactants are: - For \(\text{MnO}_4^{-}\): \(2\) - For \(\text{C}_2\text{O}_4^{2-}\): \(5\) - For \(\text{H}^{+}\): \(16\) ### Final Answer Thus, the correct coefficients of the reactants for the balanced equation are \(2, 5, 16\).
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise TRUE OR FALSE. TYPE QUESTIONS (State whether the following statements are True (T) or False (F):)|17 Videos
  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise FILL IN THE BLANKS. TYPE QUESTIONS|12 Videos
  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise ESSAY (LONG ANSWER) TYPE QUESTIONS|8 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise NCERT TEXT-BOOK EXERCISES (WITH HINTS AND SOLUTIONS )|72 Videos
  • SAMPLE QUESTION PAPER

    ICSE|Exercise Question|69 Videos

Similar Questions

Explore conceptually related problems

For the redox reaction MnO_(4)^(ө)+C_(2)O_(4)^(2-)+H^(o+)rarrMn^(2+)+CO_(2)+H_(2)O the correct coefficients of the reactions for the balanced reaction are

For the redox reaction, MnO_4^- + C_2 O_4^(2-) + H^+ rarr Mn^(2+) + CO_2 + H_2 O the correct coefficients of the reactants for the balanced reaction are respectively MnO_4^-, C_2 O_4^-, H^+ :

For the redox reaction: Fe^(2+)+ Cr_2O_7^(2-) +H^+ rarrFe^(3+) + Cr^(3+) + H_2O The correct coefficients of the reactants for the balanced reaction are

For the redox reaction: Cr_(2)O_(7)^(2-)+H^(o+)+NirarrCr^(3+)+Ni^(2)+H_(2)O The correct coefficient of the reactants for the balanced reaction are:

Complete the reaction: 2MnO_(4)^(-)+5C_(2)O_(4)^(2-) +16H^(+) to

For the redox reation MnO_(4)^(-)+C_(2)O_(4)^(2-)+H^(+)rarrMn^(2+)CO_(2)+H_(2)O The correct stoichiometric coefficients of Mno_(4)^(-),C_(2)O_(4)^(2-) and H^(+) respectively:

In the balanced equation MnO_(4)^(-)+H^(+)+C_(2)O_(4)^(2-)rarr Mn^(2+)+CO_(2)+H_(2)O , the moles of CO_(2) formed are :-

In the reaction MnO_(4)^(-)+SO_(3)^(-2)+H^(+)rarrSO_(4)^(-2)+Mn^(2+)+H_(2)O

In the reaction MnO_(4)^(-)+SO_(3)^(-2)+H^(+)rarrSO_(4)^(-2)+Mn^(2+)+H_(2)O

Consider the following reaction x MnO_(4)^(-) + C_(2)O_(4)^(2-) + zH^(+) rarr x Mn^(2+) + 2y CO_(2) + (z)/(2)H_(2)O The value of x, y and z in the reaction are respectively

ICSE-REDOX REACTIONS (OXIDATION AND REDUCTION)-OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS (Choose the correct option in the following questions:)
  1. Which of the following is a redox decomposition reaction ?

    Text Solution

    |

  2. Which of the following is not a disproportionation reaction ?

    Text Solution

    |

  3. Balance the following equation by ion electron method in the acidic me...

    Text Solution

    |

  4. Equivalent mass of C(2)O(4)^(2-) ion in the reaction, C(2)O(4)^(2-)t...

    Text Solution

    |

  5. In the titration of FeSO(4) against KMnO(4) in acidic medium, one mole...

    Text Solution

    |

  6. Calculate the oxidation number of the underlined atom in the following...

    Text Solution

    |

  7. MnO(4)^(-) is a good oxidising agent in different mediums changing to ...

    Text Solution

    |

  8. Oxidation number of Cl in CaOCl(2) (bleaching powder) is

    Text Solution

    |

  9. The oxidation state of Cr in [Cr(NH(3))(4)Cl(2)]^(+) is

    Text Solution

    |

  10. The oxidation state of chromium in the final product formed by the rea...

    Text Solution

    |

  11. What products are expected from the disproportionation reaction of hyp...

    Text Solution

    |

  12. Consider the following reaction, xMnO(4)^(-)+yC(2)O(4)^(2-)+zH^(+)to...

    Text Solution

    |

  13. Oxidation states of P in H(4)P(2)O(5),H(4)P(2)O(6),H(4)P(2)O(7) respec...

    Text Solution

    |

  14. A mixture of potassium chlorate, oxalic acid and sulphuric acid is hea...

    Text Solution

    |

  15. In which of the following reactions H(2)O(2) acts as a reducing agent?...

    Text Solution

    |

  16. The correct order of N-compounds in its decreasing order of oxidation ...

    Text Solution

    |

  17. For the redox recation MnO(4)^(-)+C(2)O(4)^(2-)+H^(+)toMn^(2+)+CO(2)...

    Text Solution

    |

  18. Which of the following reactions are disproportionation reactions ? ...

    Text Solution

    |

  19. Arrange in the increasing order of oxidation state of nitrogen for fol...

    Text Solution

    |

  20. In order to oxidise a mixture of one mole of each of FeC(2)O(4),Fe(2)...

    Text Solution

    |