Home
Class 11
CHEMISTRY
Assertion : In the reaction H2 S + HNO3...

Assertion : In the reaction `H_2 S + HNO_3 to NO + S + H_2 O, HNO_3` acts as an oxidising agent.
Reason : `HNO_3` gets oxidised to NO.

A

If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

B

If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

C

If Assertion is CORRECT but Reason is INCORRECT.

D

If Assertion is INCORRECT but Reason is CORRECT.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason statements regarding the reaction between \(H_2S\) and \(HNO_3\). ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ H_2S + HNO_3 \rightarrow NO + S + H_2O \] 2. **Determine Oxidation States**: - For \(H_2S\): - Hydrogen (H) has an oxidation state of +1 (2 H = +2). - Sulfur (S) has an oxidation state of -2. - Overall oxidation state of \(H_2S\) = +2 + (-2) = 0. - For \(HNO_3\): - Hydrogen (H) = +1, Oxygen (O) = -2. - Nitrogen (N) = +5 (to balance the overall charge). - For \(NO\): - Oxygen (O) = -2, thus Nitrogen (N) = +2. - For elemental Sulfur (S): - Oxidation state = 0. - For \(H_2O\): - Hydrogen (H) = +1, Oxygen (O) = -2. 3. **Calculate Changes in Oxidation States**: - In \(H_2S\), sulfur changes from -2 to 0 (oxidation). - In \(HNO_3\), nitrogen changes from +5 to +2 (reduction). 4. **Identify the Oxidizing Agent**: - An oxidizing agent is a substance that gets reduced while oxidizing another substance. - Here, \(HNO_3\) is reduced (from +5 to +2), meaning it gains electrons and acts as an oxidizing agent. 5. **Evaluate the Assertion and Reason**: - **Assertion**: \(HNO_3\) acts as an oxidizing agent. This is true. - **Reason**: \(HNO_3\) gets oxidized to \(NO\). This is false because \(HNO_3\) is reduced to \(NO\). 6. **Conclusion**: - The assertion is correct, but the reason is incorrect. ### Final Answer: The correct answer is that the assertion is true, but the reason is false.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise NUMERICAL PROBLEMS|4 Videos
  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise NCERT TEXT-BOOK. EXERCISES ((With Hints and Solutions)|69 Videos
  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise FILL IN THE BLANKS. TYPE QUESTIONS|12 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise NCERT TEXT-BOOK EXERCISES (WITH HINTS AND SOLUTIONS )|72 Videos
  • SAMPLE QUESTION PAPER

    ICSE|Exercise Question|69 Videos

Similar Questions

Explore conceptually related problems

H_(2)O_(2) acts as an oxidising agent in

Give a reaction in which H_(2)O acts as an oxidising agent.

In the reaction :- C+4HNO_(3)rarrCO_(2)+2H_(2)O+4NO_(2) HNO_(3) acts as :-

Can H_(2)O_(2) act both as an oxidising and a reducing agent?

Balance the following equation : NO_2 + H_2O to HNO_2 + HNO_3 .

Assertion : HNO_(2) can act both as a reducing agent and an oxidising agent. Reason : In HNO_(2) , oxidation state of nitrogen is +3 which can change from -3 to +5.

Balance the following equation : P + HNO_3 to NO_2 + H_2O + H_3PO_4 .

Assertion :- Nitrous acid (HNO_(2)) may act as an oxidising agent as well as a reducing agent. Reason :- The oxidation number of Nitrogen remains same in all the compounds.

Balance the chemical equations S+HNO_3 to H_2SO_4+ NO_2 + H_2O

Balance the following equation : HNO_3 + H_2S to NO_2 + H_2O + S .