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Assertion : Copper is unable to displac...

Assertion : Copper is unable to displace `H_2` form dil. `H_2 SO_4`
Reason : The standard electrode potential for `Cu^(2+)//Cu` system is greater than that of `H^+//1/2 H_2` system.

A

If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

B

If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

C

If Assertion is CORRECT but Reason is INCORRECT.

D

If Assertion is INCORRECT but Reason is CORRECT.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about copper's ability to displace hydrogen from dilute H₂SO₄, we will analyze both statements step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Copper is unable to displace H₂ from dilute H₂SO₄." This means that when copper is placed in dilute sulfuric acid, it does not produce hydrogen gas. 2. **Understanding the Reason**: - The reason provided is that "The standard electrode potential for the Cu²⁺/Cu system is greater than that of the H⁺/1/2 H₂ system." This implies that the tendency of copper ions to gain electrons (be reduced) is higher than that of hydrogen ions. 3. **Standard Electrode Potentials**: - The standard electrode potential (E°) for the Cu²⁺/Cu half-reaction is approximately +0.34 V. - The standard electrode potential for the H⁺/H₂ half-reaction is defined as 0.0 V. 4. **Comparing Electrode Potentials**: - Since +0.34 V (for Cu²⁺/Cu) is greater than 0.0 V (for H⁺/H₂), this indicates that copper ions have a stronger tendency to be reduced (gain electrons) than hydrogen ions. 5. **Conclusion from the Comparison**: - Because copper ions (Cu²⁺) have a greater tendency to accept electrons compared to hydrogen ions (H⁺), copper cannot displace hydrogen from dilute H₂SO₄. In other words, copper does not have the ability to donate electrons to hydrogen ions, preventing the formation of hydrogen gas. 6. **Final Evaluation**: - Both the assertion and the reason are correct. The reason correctly explains why copper cannot displace hydrogen from dilute sulfuric acid. ### Final Answer: Both the assertion and reason are correct, and the reason is the correct explanation of the assertion.
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