Home
Class 11
CHEMISTRY
While sulphur dioxide and hydrogen perox...

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why ?

Text Solution

Verified by Experts

In `SO_(2)`, the O.S. of S is + 4. Sulphur can exhibit any oxidation state in between-2 and + 6. Therefore, in `SO_(2)`, it can decrease as well as increase its oxidation state, i.e., it can undergo reduction as well as oxidation. This is why `SO_(2)` can act both as an oxidising and a reducing agent. Same is the situation with hydrogen peroxide. In `H_(2)O_(2)`, O atom is in the O.S. of -1. Oxygen can exhibit any oxidation state in between - 2 and 0 (+ 2 also when in combination with F). Therefore, in `H_(2)O_(2)`, it is free to decrease or increase its oxidation state. This is why `H_(2)O_(2)` also acts both as an oxidising and as a reducing agent.
In `O_(3)`, the O.S. of O is zero. It can only decrease its oxidation state either to -1 or to -2, but can not increase its oxidation state. Therefore, `O_(3)` acts only as an oxidant. Same is the situation with nitric acid. In `HNO_(3)`, the O.S. of N is +5, which is the highest O.S. of N. Therefore, it can only decrease its O.S. This is why `HNO_(3)` also acts only as an oxidant.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS (OXIDATION AND REDUCTION)

    ICSE|Exercise NUMERICAL PROBLEMS|4 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES

    ICSE|Exercise NCERT TEXT-BOOK EXERCISES (WITH HINTS AND SOLUTIONS )|72 Videos
  • SAMPLE QUESTION PAPER

    ICSE|Exercise Question|69 Videos

Similar Questions

Explore conceptually related problems

While sulphate dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

Water can act as an oxidising as well as a reducing agent.

Which can act as an oxidising as well as a reducing agent ?

Which of the following can act as oxidising as well as reducing agent?

Which oxide of sulfur can act as an oxidising as well as a reducing agent ?

Which of the following acts as an oxidising as well as reducing agent ?

Can PCl_5 act as an oxidising as well as a reducing agent? Justify.

In which of the solution hydrogen peroxide neither acts as oxidising agent nor reducing agent ?

Which of the following act both as an oxidising as well as reducing agent ?

Which of the following act as an oxidizing as well as a reducing agent?

ICSE-REDOX REACTIONS (OXIDATION AND REDUCTION)-NCERT TEXT-BOOK. EXERCISES ((With Hints and Solutions)
  1. Write formulas for the following compounds : Chromium (III) oxide

    Text Solution

    |

  2. Suggest a list of the substances where carbon can exhibit oxidation st...

    Text Solution

    |

  3. While sulphur dioxide and hydrogen peroxide can act as oxidising as we...

    Text Solution

    |

  4. Consider the reactions : (a) 6 CO(2) (g) + 6 H(2)O (1) to C(6) H(12)...

    Text Solution

    |

  5. The compound AgF(2) is unstable compound. However, if formed, the comp...

    Text Solution

    |

  6. Whenever a reaction between an oxidising agent and a reducing agent is...

    Text Solution

    |

  7. How do you account for the following observations ? Though alkaline ...

    Text Solution

    |

  8. How do you account for the following observations ? When concentrate...

    Text Solution

    |

  9. Identify the substance oxidised and reduced, oxidising agent and reduc...

    Text Solution

    |

  10. Consider the reactions : 2S(2)O(3)^(2-)(aq)+l(2)(s)toS(4)O(6)^(2-)(a...

    Text Solution

    |

  11. Justify giving reactions that among halogens, fluorine is the best oxi...

    Text Solution

    |

  12. Why does the following reaction occur ? XeO(6)^(4-) (aq) + 2 F^(-) (...

    Text Solution

    |

  13. Consider the reactions : (a) H(3)PO(2) (aq) + 4 AgNO(3) (aq) + 2 H...

    Text Solution

    |

  14. Balance the following redox reactions by ion-electron method. MnO(4)...

    Text Solution

    |

  15. Balance the following redox reactions by ion-electron method. MnO(4)...

    Text Solution

    |

  16. Balance the following redox reactions by ion-electron method. H(2)O(...

    Text Solution

    |

  17. Balance the following redox reactions by ion-electron method. Cr(2)O...

    Text Solution

    |

  18. Balance the following equations in basic medium by ion electron method...

    Text Solution

    |

  19. Balance the following equations in basic medium by ion electron method...

    Text Solution

    |

  20. If the elemental composition of butyric acid is found to be 54.4% C, 9...

    Text Solution

    |