Home
Class 12
CHEMISTRY
The electrode reactions for charging of ...

The electrode reactions for charging of a leas storage battery are :
`PbSO_(4) + 2e^(-) = Pb + SO_(4)^(2-)`
`PbSO_(4) + 2H_(2)O = PbO_(2) + SO_(4)^(2-) + 4H^(+) 2e^(-)`
The electrolyte in the battery is an aqueous solution of sulphuric acid. Before charging, the specific gravity of the liquid was found to be 1.11 (15.7% `H_(2)SO_(4)` by weight). After charging for 100 hours, the sp. gr. of the liquid was found to be 1.28 (36.9% `H_(2)SO_(4)` by wr.). If the battery contained two litres of the liquid, calculate the average current used for charging the battery.
NB. `(e^(-))` denotes electrons. Assume that the volume of the battery liquid remained constant during charging. 1 faraday = 96500 coulombs.

Text Solution

AI Generated Solution

To calculate the average current used for charging the lead storage battery, we will follow these steps: ### Step 1: Calculate the mass of H₂SO₄ before charging Given: - Specific gravity before charging = 1.11 - Percentage of H₂SO₄ by weight = 15.7% - Volume of the liquid = 2 liters = 2000 mL ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROLYSIS AND ELECTROLYTIC CONDUCTANCE

    RC MUKHERJEE|Exercise Examples On Conductance|13 Videos
  • ELECTROLYSIS AND ELECTROLYTIC CONDUCTANCE

    RC MUKHERJEE|Exercise Problems |47 Videos
  • DILUTE SOLUTION AND COLLIGATIVE PROPERTIES

    RC MUKHERJEE|Exercise Objective problems|36 Videos
  • ELECTROMOTIVE FORCE

    RC MUKHERJEE|Exercise EXERCISE |1 Videos
RC MUKHERJEE-ELECTROLYSIS AND ELECTROLYTIC CONDUCTANCE-Objective Problems
  1. The electrode reactions for charging of a leas storage battery are : ...

    Text Solution

    |

  2. The number of electrons involved in the reaction when one faraday of e...

    Text Solution

    |

  3. Number of electrons involved in the electrodeposited of 63.5 g of Cu...

    Text Solution

    |

  4. Faraday's laws of electrolysis are related to the

    Text Solution

    |

  5. The electric of electricity produced m kg of a subtances X. Electroche...

    Text Solution

    |

  6. 1 coulomb of electricity is passed through a solution of AlCl(3), 13.5...

    Text Solution

    |

  7. Electrochemical equivalent of a substance is 0.0006735, its eq. wt. is

    Text Solution

    |

  8. When electricity is passed through a solution of AlCl(3) and 13.5g of ...

    Text Solution

    |

  9. 3.17 g of a substance was deposited by the flow of 0.1 mole of electro...

    Text Solution

    |

  10. A current of 0.5 ampere when passed through AgNO(3) solution for 193 s...

    Text Solution

    |

  11. During electrolysis of aqueous solution of a salt pH in the space near...

    Text Solution

    |

  12. In the electrolysis of CuCl(2) solution (aq) with Cu electrodes, the w...

    Text Solution

    |

  13. The current required to diplace 0.1 g of H(2) in 10 seconds will be

    Text Solution

    |

  14. The charge of an electron is 1.6 xx 10^(-19) coulomb. How many electro...

    Text Solution

    |

  15. 96500 coulombs deposit 107.9 g of Ag from its soluton. If e = 1.6 xx 1...

    Text Solution

    |

  16. A current of 2.0 ampere is passed for 5.0 hour through a molten tin sa...

    Text Solution

    |

  17. The cost at 5 paise/KWH of operating an electric motor for 8 hours whi...

    Text Solution

    |

  18. One faraday of charge was passed through the electrolytic cells placed...

    Text Solution

    |

  19. The time required (approx) to remove electrolytically one half from 0....

    Text Solution

    |

  20. In the electrolysis of H(2)SO(4), 9.72 litres and 2.35 litres of H(2) ...

    Text Solution

    |

  21. In the electrolysis of H(2)O, 11.2 litres of H(2) was liberated at cat...

    Text Solution

    |