Home
Class 12
CHEMISTRY
Calculate the electronegativity of fluor...

Calculate the electronegativity of fluorine from following data :
`E_(H - H) = 104.2` kcal `mol^(-1)`
`E_(F - F) = 36.6` kcal `mol^(-1)`
`E_(H -F) = 134.6` kcal `mol^(-1)`
Electronegativity of H is 2.05.

Text Solution

Verified by Experts

Energy for 100% covalent bond (H-F)= `sqrt(E_(H-H) xx E_(F-F))`
=`sqrt(104.2 xx 36.6)`
=61.75 kcal
Resonance energy `(Delta)=` acutal bond energy- energy for 100% covalent bond
=134.6-61.75
=72.85 kcal
Electronegativity difference= `0.18 sqrt(Delta)`
Electronegativity of F- electronegativity of `H= 0.18 sqrt(Delta)`
Electronegativity of `F= 0.18 xx sqrt(72.85) + 2.05` = 3.586
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE AND RADIOACTIVITY

    RC MUKHERJEE|Exercise PROBLEMS (Answers bracketed with questions)|40 Videos
  • ATOMIC STRUCTURE AND RADIOACTIVITY

    RC MUKHERJEE|Exercise Objective Problems|66 Videos
  • ATOMIC WEIGHT

    RC MUKHERJEE|Exercise PROBLEMS |6 Videos

Similar Questions

Explore conceptually related problems

Calculate the electronegativity of fluorine from the following data: E_(H-H) = 104.4 kcal mol^(-1), E_(F-F) = 36.6 kcal mol^(-1) E_(H-F) = 134.3 kcal mol^(-1), chi_(H) = 2.1

Calculate the electronegativity of fluorine form the following data : E_(H-H) = 104.2 kcal "mol"^(-1), E_(C-C) =83.1 kcal "mol"^(-1) . E_(C-H) =9.8.s kcal "mo"l^(-1) Electronegativity of H=2.1 .

The electronegativity of carbon from the following data is nearly E_(H - H) = 104.2 "kcal" mol^(-1) , E_(C-C) = 83.1 kcal mol^(-1) , E_(C-H) = 98.8 kcal mol^(-1) , X_(H) = 2.1

Calculate electronegativity of carbon at Pauling scale Given that : E_(H-H) =104 .2 kcal "mol"^(-1) E_(C-C) =83.1 kcal "mol"^(-1) , E_(C-H) =98.8 kcal "mol"^(-1) . Electronegativity of hydrogen =2.1 .

Find the electron affinity of chlorine from the following data. Enthalpy of formation of LiCI is -97.5 kcal mol^(-1) , lattice energy of LiCI =- 197.7 kcal mol^(-1) . Dissociation energy of chlirine is 57.6 kcal mol^(-1) , sublimation enthalpy of lithium =+ 38.3 kcal mol^(-1) , ionisation energy of lithium =123.8 kcal mol^(-1) .

Calculate the lattice energy from the following data (given 1 eV = 23.0 kcal mol^(-1) ) i. Delta_(f) H^(ɵ) (KI) = -78.0 kcal mol^(-1) ii. IE_(1) of K = 4.0 eV iii. Delta_("diss")H^(ɵ)(I_(2)) = 28.0 kcal mol^(-1) iv. Delta_("sub")H^(ɵ)(K) = 20.0 kcal mol^(-1) ltbvrgt v. EA of I = -70.0 kcal mol^(-1) vi. Delta_("sub")H^(ɵ) of I_(2) = 14.0 kcal mol^(-1)

From the following data, calculate the standard enthalpy of formation of propane Delta_(f)H^(Theta) CH_(4) = - 17 kcal mol^(-1) Delta_(f)H^(Theta)C_(2)H_(6) =- 24 kcal mol^(-1), BE (C-H) = 99 kcal mol^(-1) (C- C) = 84 kcal mol^(-1) .

RC MUKHERJEE-ATOMIC STRUCTURE AND RADIOACTIVITY-Objective Problems
  1. Calculate the electronegativity of fluorine from following data : E...

    Text Solution

    |

  2. The frequency of a green light is 6 xx 10^(14)Hz. Its wavelength is

    Text Solution

    |

  3. The ratio of energy of a photon of 2000Å wavelength radiation to that ...

    Text Solution

    |

  4. The values of charge on the oil droplets experimentally observed were ...

    Text Solution

    |

  5. Which of the following statements is/are correct?

    Text Solution

    |

  6. For which of the following species, Bohr theory does not apply?

    Text Solution

    |

  7. The radius of the first Bohr orbit of hydrogen atom is r. The radius o...

    Text Solution

    |

  8. The electronic velocity in the fourth Bohr orbit of hydrogen is v. The...

    Text Solution

    |

  9. The ionisation potential of hydrogen atom is 13.6 eV. The energy requi...

    Text Solution

    |

  10. The energy of the second Bohr orbit in the hydrogen atom is -3.41eV. T...

    Text Solution

    |

  11. The ratio of the radii of the first three Bohr orbit in H atom is

    Text Solution

    |

  12. The ratio of the difference in energy between the first and second Boh...

    Text Solution

    |

  13. For 1=3, which value of m is not possible?

    Text Solution

    |

  14. The designation of an orbital with n=4 and l=1, is

    Text Solution

    |

  15. Which of the following orbitals is meaningless?

    Text Solution

    |

  16. Which one of the following sets of quantum number is possible for elec...

    Text Solution

    |

  17. The maximum number of electrons in an atom with quantum number n=3, l=...

    Text Solution

    |

  18. The number of orbitals in n=3 are

    Text Solution

    |

  19. If the nitrogen atom has electronic configuration 1s^(7), it would hav...

    Text Solution

    |

  20. Rutherfords experiments , which established the nuclear model of atom ...

    Text Solution

    |

  21. Total number of nodal planes are same in :

    Text Solution

    |