Home
Class 12
CHEMISTRY
Energy of an electron is given by E= -2....

Energy of an electron is given by `E= -2.178 xx 10^(-18)J ((z^(2))/(n^(2)))`. The wavelength of light required to excite an electron in a hydrogen atom from level n=1 to n=2 will be (`h= 6.62 xx 10^(-34)Js, C= 3.0 xx 10^(8) ms^(-1)`)

A

`1.214 xx 10^(-7)m`

B

`2.816 xx 10^(-7)m`

C

`6.560 xx 10^(-7)m`

D

`8.500 xx 10^(-7)m`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the wavelength of light required to excite an electron in a hydrogen atom from level n=1 to n=2, we can follow these steps: ### Step 1: Calculate the Energy at n=1 and n=2 The energy of an electron in a hydrogen atom is given by the formula: \[ E = -2.178 \times 10^{-18} \, \text{J} \left( \frac{z^2}{n^2} \right) \] For hydrogen, the atomic number \( z = 1 \). 1. **Calculate \( E_1 \) (for \( n = 1 \))**: \[ E_1 = -2.178 \times 10^{-18} \, \text{J} \left( \frac{1^2}{1^2} \right) = -2.178 \times 10^{-18} \, \text{J} \] 2. **Calculate \( E_2 \) (for \( n = 2 \))**: \[ E_2 = -2.178 \times 10^{-18} \, \text{J} \left( \frac{1^2}{2^2} \right) = -2.178 \times 10^{-18} \, \text{J} \left( \frac{1}{4} \right) = -0.5445 \times 10^{-18} \, \text{J} \] ### Step 2: Calculate the Energy Difference The energy difference \( \Delta E \) between the two levels is given by: \[ \Delta E = E_2 - E_1 \] Substituting the values: \[ \Delta E = (-0.5445 \times 10^{-18}) - (-2.178 \times 10^{-18}) = 1.6335 \times 10^{-18} \, \text{J} \] ### Step 3: Use the Energy-Wavelength Relation The relation between energy and wavelength is given by: \[ E = \frac{hc}{\lambda} \] Where: - \( h = 6.626 \times 10^{-34} \, \text{Js} \) (Planck's constant) - \( c = 3.0 \times 10^{8} \, \text{ms}^{-1} \) (speed of light) Rearranging for \( \lambda \): \[ \lambda = \frac{hc}{\Delta E} \] ### Step 4: Substitute the Values Substituting the known values into the equation: \[ \lambda = \frac{(6.626 \times 10^{-34} \, \text{Js})(3.0 \times 10^{8} \, \text{ms}^{-1})}{1.6335 \times 10^{-18} \, \text{J}} \] Calculating the numerator: \[ hc = 6.626 \times 10^{-34} \times 3.0 \times 10^{8} = 1.9878 \times 10^{-25} \, \text{Jm} \] Now substituting into the wavelength equation: \[ \lambda = \frac{1.9878 \times 10^{-25}}{1.6335 \times 10^{-18}} \approx 1.216 \times 10^{-7} \, \text{m} = 121.6 \, \text{nm} \] ### Final Answer The wavelength of light required to excite the electron from level n=1 to n=2 in a hydrogen atom is approximately **121.6 nm**. ---
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE AND RADIOACTIVITY

    RC MUKHERJEE|Exercise PROBLEMS (Answers bracketed with questions)|40 Videos
  • ATOMIC WEIGHT

    RC MUKHERJEE|Exercise PROBLEMS |6 Videos

Similar Questions

Explore conceptually related problems

Energy of an electron is given by E = - 2.178 xx 10^-18 J ((Z^2)/(n^2)) . Wavelength of light required to excite an electron in an hydrogen atom from level n = 1 to n = 2 will be (h = 6.62 xx 10^-34 Js and c = 3.0 xx 10^8 ms^-1 ).

Energy of an electron in an excited hydrogen atom is -3.4eV . Its angualr momentum will be: h = 6.626 xx 10^(-34) J-s .

RC MUKHERJEE-ATOMIC STRUCTURE AND RADIOACTIVITY-Objective Problems
  1. The orbital angular momentum of an electron in2sorbital is

    Text Solution

    |

  2. For a d-electron, the orbital angular momentum is

    Text Solution

    |

  3. .(13)Al^(27) is a stable isotope. .(13)Al^(29) is expected to disinteg...

    Text Solution

    |

  4. Which of the following relates to photon both as wave motion and as a...

    Text Solution

    |

  5. The kinetic energy of an electron in the second Bohr orbit of a hydrog...

    Text Solution

    |

  6. Energy of an electron is given by E= -2.178 xx 10^(-18)J ((z^(2))/(n^(...

    Text Solution

    |

  7. The first ionisation potential of Na is 5.1eV. The value of electrons ...

    Text Solution

    |

  8. The correct set of four quantum numbers for valence electrons of rubid...

    Text Solution

    |

  9. Which of the following is the energy of a possible excited state of h...

    Text Solution

    |

  10. A stream of electrons from a heated filament was passed between two ch...

    Text Solution

    |

  11. Which of the following atoms has the highest first ionisation energy ?

    Text Solution

    |

  12. P is the probability of finding the 1s electron of hydrogen atom in a ...

    Text Solution

    |

  13. The radius of the second Bohr orbit for hydrogen atom is : (Plank'c c...

    Text Solution

    |

  14. The group having isoelectronic species is :-

    Text Solution

    |

  15. For the given orbital in column 1, the only correct combination for an...

    Text Solution

    |

  16. For hydrogen atom, the only correct combination is

    Text Solution

    |

  17. Bombardment of Al by alpha-particles leads to artificial disintegratio...

    Text Solution

    |

  18. In the nuclear transmutation : .(4)^(9) Be + X rarr (4) ^(8) Be +Y ...

    Text Solution

    |

  19. A plot of the number of neutrons (n) against the number of protons (p...

    Text Solution

    |

  20. Ejection of the photoelectron from metal in the photoelectric effect e...

    Text Solution

    |