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Two moles of a gas at 1 bar and 298 K ar...

Two moles of a gas at 1 bar and 298 K are compressed at constant Temperature by use of a constant pressure of 5 bar. How much work is done on the gas ? If the compression is driven by a 100-kg mass, how far will it fall in the earth's gravitational field ? `(g=9.8 ms^(-2))`

Text Solution

Verified by Experts

We have, for an irreversible isothermal process,
`W=-p_(2)(V_(2)-V_(1))` …(Eqn. 2)
`=-p_(2)((nRT)/(p_(2))-(nRT)/(p_(1)))`
`=nRT(1-(p_(2))/(p_(1)))`
`-2xx8.314xx298 (1-(5)/(1))`
`=19820 J`.
Further, W=mgh …(Eqn. 3b)
`h=(W)/(mg)=(19820)/(100xx9.8)m`
`=20.22` m.
The following problems are based on thermochemical calculations. In dealing with these problems, we apply the inspection method, as discussed previously.
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RC MUKHERJEE-CHEMICAL THERMODYNAMICS-Objective problems
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  9. {:[(H(2)(g)+(1)/(2)O(2)(g)=H(2)O(g),DeltaH=-241.8kJ),(C(2)H(2)(g)+2(1)...

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  11. The temperature of a 5mL of strong acid increases by 5^(@) when 5 mL o...

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  12. Heat of neutralisation of a strong acid by a strong base is equal to D...

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  13. In which case of mixing of a strong acid and a base each of 1N concent...

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  15. The dissociation energy of CH(4) and C(2)H(6) are respectively 360 and...

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  16. In which of the following cases entropy decreases?

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  17. In which of the following reactions DeltaS is positive?

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  18. The Delta G in the process of melting of Ice at -15^(@) C is

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  19. In a reaction , DeltaH and DeltaS both are more than zeron. In which o...

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  20. In which case is a reaction possible at any temperature ?

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  21. In which case is a reaction impossible at any temperature ?

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