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Assertion : The alkaline earth metal hyd...

Assertion : The alkaline earth metal hydroxides are more basic than the corresponding alkali metal.
Reason : The ionisation enthalpies of alkaline earth metals are much lower than those of alkali metals.

A

If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

B

If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

C

If Assertion is CORRECT but Reason is INCORRECT.

D

Both Assertion and reason are INCORRECT

Text Solution

AI Generated Solution

The correct Answer is:
To determine whether the assertion and reason provided in the question are true or false, we will analyze both statements step by step. ### Step 1: Analyze the Assertion **Assertion:** The alkaline earth metal hydroxides are more basic than the corresponding alkali metal hydroxides. **Analysis:** - Alkaline earth metals (Group 2) include elements like Be, Mg, Ca, Sr, and Ba. - Alkali metals (Group 1) include elements like Li, Na, K, Rb, and Cs. - The hydroxides of alkali metals (e.g., NaOH, KOH) are known to be strong bases and are more soluble in water compared to alkaline earth metal hydroxides (e.g., Ca(OH)₂, Sr(OH)₂). - Generally, alkali metal hydroxides are more basic than alkaline earth metal hydroxides due to their higher solubility and the greater availability of hydroxide ions in solution. **Conclusion for Assertion:** The assertion is **false**. ### Step 2: Analyze the Reason **Reason:** The ionization enthalpies of alkaline earth metals are much lower than those of alkali metals. **Analysis:** - Ionization enthalpy refers to the energy required to remove an electron from an atom in the gaseous state. - For alkali metals, the general electronic configuration is ns¹, while for alkaline earth metals, it is ns². - Alkali metals have lower ionization enthalpies compared to alkaline earth metals because the removal of one electron from alkali metals leads to a stable noble gas configuration. - In contrast, removing an electron from alkaline earth metals requires more energy because they have a more stable filled subshell (ns²). **Conclusion for Reason:** The reason is also **false**. ### Final Conclusion Both the assertion and the reason are false. Therefore, the correct answer to the question is **D** (Both Assertion and Reason are false). ---
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