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Bromoethane on treatment with alcoholic ...

Bromoethane on treatment with alcoholic KOH gives

A

ethyl alcohol

B

butane

C

methane

D

ethylene

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The correct Answer is:
To solve the question regarding the reaction of bromoethane with alcoholic KOH, we can follow these steps: ### Step 1: Identify the Reactants The reactant in this case is bromoethane (C2H5Br) and the reagent is alcoholic KOH. ### Step 2: Understand the Reaction Type Alcoholic KOH is known to act as a dehydrohalogenating agent. This means it will facilitate the elimination of hydrogen and bromine from bromoethane. ### Step 3: Elimination of HBr In the reaction, a hydrogen atom (H) from one carbon and the bromine atom (Br) from the adjacent carbon are eliminated. This results in the formation of HBr as a byproduct. ### Step 4: Formation of Ethene The elimination of H and Br leads to the formation of a double bond between the two carbon atoms, resulting in the formation of ethene (C2H4). ### Step 5: Write the Balanced Equation The balanced equation for the reaction can be written as: \[ \text{C}_2\text{H}_5\text{Br} + \text{KOH (alc)} \rightarrow \text{C}_2\text{H}_4 + \text{KBr} + \text{H}_2\text{O} \] ### Conclusion Thus, the product of the reaction of bromoethane with alcoholic KOH is ethene. ---
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An organic compound (A) C_(4)H_(9)Cl on reacting with aqueous KOH gives (B) and on reaction with alcoholic KOH gives (C ), which is also formed on passing the vapours of (B) over the heated copper. The compound (C ) readily decolourises bromine water. Ozonolysis of (C ) gives two compounds (D) and (E ). Compound (D) reacts with NH_(2)OH to give (F) and compound (E ) reacts with NaOH to have an alcohol (G) and sodium salt (H) of an acid. (D) can also be prepared form propyne on treatment with water in the presence of Hg^(2+) and H_(2)SO_(4) . Identify (A) to (H) with proper reasoning.

A compound A with molecular formula C_(15)H_(13)Cl gives a white precipitate on adding silver nitrate solution A on reacting with alcoholic KOH gives compound B as the main product. B on ozonolysis gives C and C gives Cannizaro reaction but not aldol condensation. D gives aldol condensation but not Cannizaro react A is :

ICSE-HYDROCARBONS -OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS
  1. The compound with the highest boiling point is

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  2. Liquid hydrocarbon is converted to a mixture of gaseous hydrocarbons b...

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  3. Bromoethane on treatment with alcoholic KOH gives

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  4. Dehydrohalogenation involves removal of the halogenn atom together wit...

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  5. The compound that decolourises alk. KMnO4 is

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  6. The product formed when but-1-ene is subjected to HBr in the presence ...

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  7. CH2 = CHCl reacts with HCl to form

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  8. The final products formed by ozonolysis of compound R - CH = CR2 is

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  9. What is Baeyer's reagent ?

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  10. Dilute aqueous KMnO4 at room temperature reacts with R-CH=CH-R to giv...

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  11. Acetylene can be prepared from

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  12. Number of acidic hydrogen atoms in but-1-yne is

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  13. Which of the following reacts with metal by displacing the hydrogen at...

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  14. In the above reaction X is

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  15. Which one of the following reagents distinguish ethylene from acetylen...

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  16. A hydrocarbon that reacts with sodium in liquid NH3 is

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  17. A metallic carbide on treatment with water gives a colourless gas whic...

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  18. In alkenes, pi -electrons forming carbon-carbon pi-bond are

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  19. The process C7H16 underset(670K) overset(Pt)(to) C6H5CH3 + 4H2 is a

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  20. Which of the following when used as a fuel have the maximum tendency t...

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