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In alkenes, pi -electrons forming carbon...

In alkenes, `pi` -electrons forming carbon-carbon `pi`-bond are

A

localised

B

delocalised over the entire molecule

C

may or may not be delocalised

D

none of the above

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The correct Answer is:
To solve the question regarding the nature of pi electrons in alkenes, we can break down the analysis step by step: ### Step-by-Step Solution: 1. **Understanding Alkenes**: - Alkenes are hydrocarbons that contain at least one carbon-carbon double bond (C=C). The double bond consists of one sigma (σ) bond and one pi (π) bond. 2. **Identifying Pi Electrons**: - The pi bond is formed by the sideways overlap of p-orbitals from adjacent carbon atoms. The electrons in this bond are referred to as pi electrons. 3. **Localization vs. Delocalization**: - **Localized Pi Electrons**: These are pi electrons that are confined to a specific bond between two carbon atoms and do not participate in resonance or spread over other parts of the molecule. - **Delocalized Pi Electrons**: These are pi electrons that can move between multiple atoms, typically seen in conjugated systems where there are alternating single and double bonds. 4. **Analyzing Examples**: - **Example 1**: In a molecule like buta-1,3-diene (CH2=CH-CH=CH2), the pi electrons can be delocalized. The double bonds can interact, allowing the pi electrons to be shared across multiple carbon atoms. - **Example 2**: In a simple alkene like butene (CH2=CH-CH2-CH3), the pi electrons are localized between the two carbon atoms involved in the double bond, as there are no other pi bonds to allow delocalization. 5. **Conclusion**: - From the analysis, we see that in alkenes, the pi electrons can either be localized (as in butene) or delocalized (as in buta-1,3-diene). Therefore, the correct answer to the question is that the pi electrons forming carbon-carbon pi bonds in alkenes "may or may not be delocalized." ### Final Answer: The correct option is C: "may or may not be delocalized."
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ICSE-HYDROCARBONS -OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS
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  2. A metallic carbide on treatment with water gives a colourless gas whic...

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  3. In alkenes, pi -electrons forming carbon-carbon pi-bond are

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  4. The process C7H16 underset(670K) overset(Pt)(to) C6H5CH3 + 4H2 is a

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  7. Which of the following when treated with a Grignard reagent yield (s) ...

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  8. A compound decolourises Baeyer's reagent and gives a mixture of propan...

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  9. Nitration of benzene by nitric acid and sulphuric acid is

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  10. Benzene vapour mixed with air when passed over V2O5 catalyst at 775 K...

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  11. Which of the following statements is correct for benzene ?

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  12. In the Friedel-Crafts acylation, the attacking species is

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  13. Which of the following is not the characteristics of an arene?

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  14. In the reaction HIO3 acts as

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  15. Propyne and propene can be distinguished by conc. H2SO4 Br2 in "CCl"...

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  16. Acetylene does not react with

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  17. But-1-ene may be converted to butane by reaction with

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  18. 2-methylbutane on reacting with bromine in the presence of sunlight gi...

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  19. Presence of a nitro group in a benzene ring

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  20. In the following sequence of reactions, the alkene affords the compoun...

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