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In the reaction HIO3 acts as...

In the reaction `HIO_3` acts as

A

A. a catalyst

B

B. a halogen carrier

C

C. an oxidizing agent

D

D. a reducing agent.

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The correct Answer is:
To determine the role of `HIO3` in the reaction involving D-glucose, we can follow these steps: ### Step 1: Identify the Reactant The reactant in this reaction is D-glucose, which has the molecular formula C₆H₁₂O₆. ### Step 2: Determine the Oxidation State of Carbon in Glucose To find the oxidation state of carbon in glucose, we can use the formula: \[ 6X + 12(+1) + 6(-2) = 0 \] Where: - \( X \) is the oxidation state of carbon. - There are 6 carbon atoms, 12 hydrogen atoms, and 6 oxygen atoms. Calculating: \[ 6X + 12 - 12 = 0 \] \[ 6X = 0 \] \[ X = 0 \] Thus, the oxidation state of carbon in glucose is 0. ### Step 3: Identify the Products of the Reaction In the reaction, one of the products is formic acid (HCOOH) and another product is formaldehyde (HCHO). ### Step 4: Determine the Oxidation State of Carbon in the Products 1. **For Formic Acid (HCOOH)**: \[ X + 2(+1) + 2(-2) = 0 \] \[ X + 2 - 4 = 0 \] \[ X - 2 = 0 \] \[ X = +2 \] The oxidation state of carbon in formic acid is +2. 2. **For Formaldehyde (HCHO)**: \[ X + 2(+1) + (-2) = 0 \] \[ X + 2 - 2 = 0 \] \[ X = 0 \] The oxidation state of carbon in formaldehyde is 0. ### Step 5: Analyze the Changes in Oxidation States - In glucose, the oxidation state of carbon is 0. - In formic acid, the oxidation state of carbon is +2. - In formaldehyde, the oxidation state of carbon remains 0. ### Step 6: Conclusion Since 5 out of the 6 carbon atoms in glucose are oxidized from an oxidation state of 0 to +2, we can conclude that `HIO3` (or `HIO4` as mentioned in the transcript) is acting as an oxidizing agent in this reaction. It facilitates the oxidation of glucose. ### Final Answer `HIO3` acts as an oxidizing agent in the reaction involving D-glucose. ---
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