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State the difference between Schottky an...

State the difference between Schottky and Frenkel defects. Which of these two changes the density of the solid ?

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### Step-by-Step Solution: 1. **Definition of Schottky Defect**: - A Schottky defect occurs when a pair of oppositely charged ions (cation and anion) leave the crystal lattice, creating vacancies. This results in a decrease in the density of the solid because the mass of the solid decreases while the volume increases due to the absence of these ions. 2. **Definition of Frenkel Defect**: - A Frenkel defect occurs when a cation leaves its lattice site and occupies an interstitial site within the crystal structure. In this case, the overall mass of the solid remains the same, and the volume does not change significantly because the ion is still part of the solid, just relocated. ...
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When an atom or an ion is missing from its nomal lattice site a lattice vacanecy (Schottky defect) is created. In stoichmeteric ionic crystals, a vacancy of one ion has to be accompanied by the vacancy of the oppositely charge ion in order to maintain electrical neutrality. In a Frenkel defect an ion leaves its position in the lattice and occupies an interstitial void. This id the Frenkel defect commonly found along with the Schottky defects and interstitial. In pure alkali halides. Frenked defects are not found since the ions cannot get into the interstitial sites. Frenkel defects are found in silver halides because of the small size of the Ag^(+) ion. Unike Schottky defects, Frenkel defect do not change the density of the solids. in certain ionic solids (e.g., AgBr) both schottky and Frenkel defect occur. The Defects idiscussed above do not disturb the stoichiometery of the crystalline material. there is large variety of non-stoichiometric inorganic solids which contains an excess or deficienty of one of the elements. Such solids showing deviations from the ideal stoichiometric composition from an important group of solids. For example in the vanadium oxide, VO_(x),x can be anywehere between 0.6 and 1.3 there are solids such as difficult to prepare in the soichiometric omposition thus, the ideal composition in compounds such as FeO is difficult to obtain (normally we get a compositiion of Fe(0.95) O but it may range from Fe_(0.93) O to Fe_(0.96)O ). Non-stoichiometric behavious is most commonly found for transition metal compounds through is also known for some lathanoids and actinoids. Zinc oxide loses oxygen reversible at high temperature and turns yellow in colour. the excess metal is accomodated interstitial, giving rise to electrons trapped in the neighbourhood, the enchanced electrical conductivity of the non-stoichiometric ZnO arises from these electrons. Anion vacancies in alkali halides are produced by heating the alkali halid crystals in an atmosphere of the alkali metal vapour. when the metal atoms deposit on the surface they diffuse into the cystal and after ionisation the alkali metal ion occupies cationic vacancy whereas electron occupies anionic vacancy. Electrons trapped i anion vacancies are referred to as F-centers (From Farbe the German word for colouf) that gives rise to interesting colour in alkali halides. Thus, the excess of potassium i KCl makes the crystal appear violet and the excess of lithium in LiCl makes it pink. Which of the following is most appropritate crystal to show Fremkel defect ?

ICSE-SOLID STATE-EXERCISE (PART-II DESCRIPTIVE QUESTIONS) (SHORT ANSWER QUESTIONS)
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  2. Briefly describe the radius ratio rules.

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  3. Explain briefly the superconductivity.

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  4. Explain each of the following with a suitable example: Paramagnetism .

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  5. Explain each of the following with a suitable example: Piezoelectric e...

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  6. Explain the nature of the crystal defect produced when NaCl is doped w...

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  7. Prove that the actual volume occupied by a bcc arrangement is 68% only...

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  8. How much is the empty space present in a primitive unit cell? Also cal...

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  9. Addition of CdCl2 to the crystals of AgCl will produce Schottky defect...

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  10. Distinguish between crystal lattice and unit cell.

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  11. Give reasons Silicon doped with phosphorus, gives an n-type semiconduc...

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  12. Give reasons The electrical conductivity of a metal decreases with ris...

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  13. Account for the Silicon is an insulator but silicon doped with phospho...

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  14. Account for the Some of the very old glass objects appear slightly mil...

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  15. State the difference between Schottky and Frenkel defects. Which of th...

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  16. What are molecular crystals ? Name the forces which are holding the co...

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  17. What are metallic crystals ?

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  18. Describe briefly the structure of copper metal.

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  19. Draw a neat diagram for NaCl structure.

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  20. Discuss the structure of diamond.

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