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How are XeO(3) and XeOF(4) prepared?...

How are `XeO_(3)` and `XeOF_(4)` prepared?

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Statement-1 : Hydrolysis of XeF_(6) represents a redox reaction. Statement-2 : The products of hydrolysis are XeOF_(4) and XeO_(3) where the oxidation states of all elements remain the same as it was in the reacting state.

If the central atom is of third row or below this in the periodic table, then lone pair will occupy a stereochemically inactive s-orbital and bonding will be through almost pure p-orbitals and bond angles are nearly 90^(@) , if the substituent's electronegativity value is le 2.5 . The hybridisation of atomic orbitals of central atom "Xe" in XeO_(4), XeO_(2)F_(2) and XeOF_(4) respectively.

If the central atom is of third row or below this in the periodic table, then lone pair will occupy a stereochemically inactive s-orbital and bonding will be through almost pure p-orbitals and bond angles are nearly 90^(@) , if the substituent's electronegativity value is le 2.5 . The hybridisation of atomic orbitals of central atom "Xe" in XeO_(4), XeO_(2)F_(2) and XeOF_(4) respectively.

(a) Write the balanced chemical equations for obtaining XeO_(3) " and " XeOF_(4) "from "XeF_(6). (b) Account for the followingk : (i) H_(2)S is less acidic then H_(2) Te. (ii) H_(3)PO_(2) has reducing nature. (iii) SO_(2) is an air pollutant.

Assertion (A): Sodium perxenate (Na_(4)XeO_(6)) reacts with NaF in acidic medium to give XeO_(3) and F_(2) Reason (R ): XeO_(6)^(4-) is a stronger oxidant than F_(2) .

Number of lone pairs (s) in XeOF_(4) is/are

Molecular shape of ClF_(3) , l_(3)^(-) and XeO_(3) respectively are

Predict the shape of the following Xenon compounds (a) XeO_(3) (b) XeOF_(4) (c ) XeO_(2)F_(2) .

Shape of XeOF_(4) is

In case of XeO_(2) F_(2) and XeF_(6) , Xe is with

ICSE-P-BLOCK ELEMENTS-EXERCISE (PART-II)(DESCRIPTIVE QUESTIONS)(SHORT ANSWER QUESTIONS)
  1. Fluorine is more electronegative than iodine atom, yet HF has lower ac...

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  2. State the trends observed in case of each of the following: (i) Oxid...

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  3. Give reasons for the following: (i) Binary compounds of oxygen and f...

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  4. What happens when : (i) Cl2 is passed through hot NaOH. (ii) Cl2 ...

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  5. Noble gases are relatively inert elements. Give reasons.

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  6. Why ease to liquefy noble gases increases with increase in atomic numb...

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  7. Give reasons which prompted Bartlett to react xenon with fluorine to f...

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  8. How are XeO(3) and XeOF(4) prepared?

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  9. Explain the following : Only higher members of group 18 of the perio...

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  10. Explain the following : Hydrogen fluoride is much less volatile than...

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  11. Explain the following : Interhalogen compounds are strong oxidising ...

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  12. Explain the hybridization in XeF2. Also draw its molecular structure.

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  13. Explain the hybridization in XeF4. Also draw its molecular structure.

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  14. Explain the hybridization in XeF(6-) . Also draw its molecular structu...

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  15. Explain the hybridization in XeOF(2-) . Also draw its molecular struct...

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  16. Give the shapes of CIF3, BrF5 and IF7 using VSEPR theory.

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  17. Write the hybridization and also draw their molecular structures : (...

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  18. Give equations for the preparation of XeO2F2, XeOF4 and XeO2F2.

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  19. Give the molecular shapes of XeF2, XeF4, XeF6 and XeO3.

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  20. How are xenon fluorides prepared ? Discuss their behaviour towards wat...

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