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The more paramagnetic in the following i...

The more paramagnetic in the following is

A

Mn

B

Cr

C

`Fe^(2+)`

D

`Fe^(3+)`

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The correct Answer is:
To determine which of the given elements or ions is the most paramagnetic, we need to analyze their electronic configurations and count the number of unpaired electrons. Paramagnetism arises from the presence of unpaired electrons in an atom or ion. ### Step-by-Step Solution: 1. **Identify the Elements and Their Electronic Configurations**: - Manganese (Mn): Atomic number = 25 - Electronic configuration: \( [Ar] 3d^5 4s^2 \) - Chromium (Cr): Atomic number = 24 - Electronic configuration: \( [Ar] 3d^5 4s^1 \) - Iron (Fe): Atomic number = 26 - Electronic configuration: \( [Ar] 3d^6 4s^2 \) - Iron (Fe²⁺): When iron loses 2 electrons, it loses the 4s electrons first. - Electronic configuration: \( [Ar] 3d^6 \) - Iron (Fe³⁺): When iron loses 3 electrons, it loses both 4s and one 3d electron. - Electronic configuration: \( [Ar] 3d^5 \) 2. **Count the Unpaired Electrons**: - **Manganese (Mn)**: - Configuration: \( 3d^5 4s^2 \) - Unpaired electrons: 5 (all 5 d electrons are unpaired) - **Chromium (Cr)**: - Configuration: \( 3d^5 4s^1 \) - Unpaired electrons: 6 (5 unpaired d electrons + 1 unpaired s electron) - **Iron (Fe²⁺)**: - Configuration: \( 3d^6 \) - Unpaired electrons: 4 (the 6 electrons fill the d orbitals, resulting in 4 unpaired electrons) - **Iron (Fe³⁺)**: - Configuration: \( 3d^5 \) - Unpaired electrons: 5 (all 5 d electrons are unpaired) 3. **Compare the Number of Unpaired Electrons**: - Manganese: 5 unpaired electrons - Chromium: 6 unpaired electrons - Iron (Fe²⁺): 4 unpaired electrons - Iron (Fe³⁺): 5 unpaired electrons 4. **Conclusion**: - The element with the highest number of unpaired electrons is Chromium (Cr) with 6 unpaired electrons. Therefore, Chromium is the most paramagnetic among the given options. ### Final Answer: **Chromium (Cr) is the more paramagnetic of the following.**

To determine which of the given elements or ions is the most paramagnetic, we need to analyze their electronic configurations and count the number of unpaired electrons. Paramagnetism arises from the presence of unpaired electrons in an atom or ion. ### Step-by-Step Solution: 1. **Identify the Elements and Their Electronic Configurations**: - Manganese (Mn): Atomic number = 25 - Electronic configuration: \( [Ar] 3d^5 4s^2 \) - Chromium (Cr): Atomic number = 24 ...
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ICSE-d- AND- f- BLOCK ELEMENTS-EXERCISE (PART-I)(OBJECTIVE QUESTIONS)(THE CORRECT ALTERNATIVE FROM THE CHOICES GIVEN : )
  1. The incorrect statement regarding transition elements is

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  2. The element which does not show +4 oxidation state is:

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  3. The more paramagnetic in the following is

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  4. Electronic configuration of a transition element X in + 3 oxidation st...

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  5. The electronic configuration of Cu(II) is 3d^9 whereas that of Cu(I) i...

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  6. Metallic radii of some transition elements are given below. Which of t...

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  7. Generally transition elements form coloured salts due to the presence ...

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  8. On addition of small amount of KMnO(4) to concentrated H(2)SO(4), a g...

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  9. The magnetic nature of elements depends on the presence of unpaired el...

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  10. Which of the listed oxidation states is common for all lanthanoids ?

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  11. Which of the following reactions are disproportionation reactions ? ...

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  12. When KMnO4 solution is added to oxalic acid solution, the decolourisat...

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  13. There are 14 elements in actinoid series. Which of the following eleme...

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  14. KMnO(4) acts as an oxidising agent in acidic medium. The number of mol...

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  15. Which of the following is amphoteric oxide? Mn(2)O(7), CrO(3), C...

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  16. Gadolinium belongs to 4f series. It's atomic number is 64. Which of th...

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  17. Interstitial compounds are formed when small atoms are trapped inside ...

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  18. The magnetic moment is associated with its spin angular momentum and o...

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  19. KMnO(4) acts as an oxidising agent in alkaline medium. When alkaline K...

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  20. Which of the following statements is not correct ?

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