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The magnetic nature of elements depends ...

The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition element which shows highest magnetic moment.

A

`3d^7`

B

`3d^5`

C

`3d^8`

D

`3d^2`

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The correct Answer is:
To determine the configuration of the transition element that shows the highest magnetic moment, we need to analyze the number of unpaired electrons in each given electronic configuration. The magnetic moment is directly related to the number of unpaired electrons, with more unpaired electrons resulting in a higher magnetic moment. ### Step-by-Step Solution: 1. **Identify the Configurations**: We have four configurations to analyze: - Option 1: 3d⁷ - Option 2: 3d⁵ - Option 3: 3d⁸ - Option 4: 3d⁹ 2. **Determine the Number of Unpaired Electrons**: - **For 3d⁷**: - The filling order is: ↑ ↑ ↑ ↑ (first 5 electrons are unpaired) and then the next two electrons will pair up. - Thus, there are 3 unpaired electrons. - **For 3d⁵**: - All five electrons are unpaired: ↑ ↑ ↑ ↑ ↑. - Thus, there are 5 unpaired electrons. - **For 3d⁸**: - The filling order is: ↑ ↑ ↑ ↑ (first 5 electrons are unpaired) and then the next three electrons will pair up. - Thus, there are 2 unpaired electrons. - **For 3d⁹**: - The filling order is: ↑ ↑ ↑ ↑ (first 5 electrons are unpaired) and then the next four electrons will pair up. - Thus, there are 1 unpaired electron. 3. **Calculate the Magnetic Moment**: - The formula for calculating the magnetic moment (μ) is: \[ μ = \sqrt{n(n + 2)} \text{ Bohr magnetons} \] - **For 3d⁷** (3 unpaired electrons): \[ μ = \sqrt{3(3 + 2)} = \sqrt{15} \text{ Bohr magnetons} \] - **For 3d⁵** (5 unpaired electrons): \[ μ = \sqrt{5(5 + 2)} = \sqrt{35} \text{ Bohr magnetons} \] - **For 3d⁸** (2 unpaired electrons): \[ μ = \sqrt{2(2 + 2)} = \sqrt{8} \text{ Bohr magnetons} \] - **For 3d⁹** (1 unpaired electron): \[ μ = \sqrt{1(1 + 2)} = \sqrt{3} \text{ Bohr magnetons} \] 4. **Compare the Magnetic Moments**: - 3d⁷: μ = √15 - 3d⁵: μ = √35 - 3d⁸: μ = √8 - 3d⁹: μ = √3 5. **Conclusion**: The configuration with the highest magnetic moment is 3d⁵, which has 5 unpaired electrons. ### Final Answer: The configuration of the transition element that shows the highest magnetic moment is **3d⁵** (Option 2). ---

To determine the configuration of the transition element that shows the highest magnetic moment, we need to analyze the number of unpaired electrons in each given electronic configuration. The magnetic moment is directly related to the number of unpaired electrons, with more unpaired electrons resulting in a higher magnetic moment. ### Step-by-Step Solution: 1. **Identify the Configurations**: We have four configurations to analyze: - Option 1: 3d⁷ - Option 2: 3d⁵ - Option 3: 3d⁸ ...
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ICSE-d- AND- f- BLOCK ELEMENTS-EXERCISE (PART-I)(OBJECTIVE QUESTIONS)(THE CORRECT ALTERNATIVE FROM THE CHOICES GIVEN : )
  1. The electronic configuration of Cu(II) is 3d^9 whereas that of Cu(I) i...

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  2. Metallic radii of some transition elements are given below. Which of t...

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  3. Generally transition elements form coloured salts due to the presence ...

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  4. On addition of small amount of KMnO(4) to concentrated H(2)SO(4), a g...

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  5. The magnetic nature of elements depends on the presence of unpaired el...

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  6. Which of the listed oxidation states is common for all lanthanoids ?

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  7. Which of the following reactions are disproportionation reactions ? ...

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  8. When KMnO4 solution is added to oxalic acid solution, the decolourisat...

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  9. There are 14 elements in actinoid series. Which of the following eleme...

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  10. KMnO(4) acts as an oxidising agent in acidic medium. The number of mol...

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  11. Which of the following is amphoteric oxide? Mn(2)O(7), CrO(3), C...

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  12. Gadolinium belongs to 4f series. It's atomic number is 64. Which of th...

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  13. Interstitial compounds are formed when small atoms are trapped inside ...

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  14. The magnetic moment is associated with its spin angular momentum and o...

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  15. KMnO(4) acts as an oxidising agent in alkaline medium. When alkaline K...

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  16. Which of the following statements is not correct ?

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  17. When acidified K2Cr2O7 solution is added to Sn^(2+) salts, then Sn^(2+...

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  18. Highest oxidation state of manganese in fluorides is +4(MnF4) but hig...

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  19. Although Zirconium belongs to 4d transition series and Hafnium to 5d t...

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  20. Why is HCl not used to make the medium acidic in oxidation reactions o...

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