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How and you account for the following : ...

How and you account for the following :
(i) Cabalt (II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidised.
(ii) The transition elements exhibit high enthalpy of atomization.
(iii) of the `d^4` species, `Cr^(2+)` is strongly reducing while Mn (III) is strongly oxidsing .

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Account for the following statements : (i) Co (ii) is stable in aqueous solution but in the presence of strong ligands and air it can get oxidised to Co (III) (at. No Co=27) (ii) of the d^4 species Cr (II) is strongly reducing but Mn (III) is strongly oxidising (at. no Cr= 24 , Mn = 25, Co = 27)

How would you account for the following : (i) Out of the d^(4) species, Cr^(2+) is strongly reducing while manganese (III) is strongly oxidising. (ii) Cobalt (II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidized. (iii) The d^(1) configuration is very unstable in ions.

How would you account for the following: A) Of the d^(4) species Cr^(2+) is strongly reducing while manganese(III) is strongly oxidizing. B) Cobalt(II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidized. C) The D^(1) configuration is very unstable in ions.

Account for the following (i) Co(II) is stable in aqueous solution but in the presence of strong ligand and air , it can get oxidized to Co(III) . (ii) [Ni(CN)_(4)]^(2-) is square planar and diamagnetic whereas [NiCl_(4)]^(2-) is tetrahedral and paramagnetic .

How would you account for the following : (i) Cr^(2+) is reducing in nature while with the same d-orbital configuration (d^(4)),Mn^(2+) is oxidising in nature. (ii) In the transition series of metals, the metal which exhibits the greatest number of oxidation states occurs in the middle of the series.

(a) Account for the following : (i) Cu^(+) is unstable in an aqueous solution. (ii) Transition metals form complex compounds. (b) Complete the following equation: Cr_(2)O_(7)^(2-)+8H^(+)+3NO_(2)^(-)rarr

Assign reasons for the following : (i) Cu(I) ion is not known to exist in aqueous solutions. (ii) Transition metals are much harder than the alkali metals. (iii) From element to element, actinoid contraction is greater than the lanthanoid contraction.

Give reasons for the following: (i) Transition metals exhibit a wide range of oxidation states. (ii) Cobalt (II) is very stable in aqueous solutions but gets easily oxidised in the presence of strong ligands. (iii) Actinoids exhibit a greater range of oxidation states than lanthanoids.

How would you account for the following ? (i) With the same d-orbital configuration (d^(4)) Cr^(2+) is reducting agent while Mn^(3+) is an oxidizing agent. (ii) The actionoids exhibits a larger numbe of oxidation states than the corresponding members in the lanthanoid series. (iii) Most of the transition metal ions exhibit characteristic in colours in aqueous solutions.

How would you account for the following ? (i) With the same d-orbital configuration (d^(4)) Cr^(2+) is reducting agent while Mn^(3+) is an oxidizing agent. (ii) The actionoids exhibits a larger numbe of oxidation states than the corresponding members in the lanthanoid series. (iii) Most of the transition metal ions exhibit characteristic in colours in aqueous solutions.

ICSE-d- AND- f- BLOCK ELEMENTS-EXERCISE (PART-II) (DESCRIPTIVE QUESTIONS)(LONG ANSWER QUESTIONS)
  1. Assign reasons for the following : (b) The ionization energy of 5d e...

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  2. Assign reasons for the following : Write equations for the preparati...

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  3. Assign reasons for the following: Sc^(3+) ion is colourless while Cr...

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  4. Why are Mn^(2+) compounds more stable than Fe^(2+) towards oxidation t...

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  5. Assign reasons for the following: Cu(I) compounds are white and diam...

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  6. Assign reasons for the following: Why is the chemistry of all lantha...

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  7. Assign reasons for the following: What is lanthanoid contraction ? E...

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  8. How and you account for the following : (i) Cabalt (II) is stable in...

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  9. Why Sm^(2+) , Eu^(2+) and Yb^(2+) ions are good reducing agents , but ...

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  10. Compare the properties of lanthanoids and actinoids.

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  11. Given below are the electrode potential values, E^(Theta) for some of ...

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  12. Complete the following chemical reaction equations : (i) Cr(2)O(7)^(...

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  13. Decribe the general trends in the following properties of the first se...

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  14. Assign reasons for each of the following (i) Trasitiono elements exh...

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  15. (a) Complete the following chemical reaction equations : (i) MnO(4(a...

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  16. Explain the following observations about the transition/ inner-transit...

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  17. Complete the follwing chemical equations for reactions : (i) Fe^(@+...

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  18. Give an explanation for each of the following observations: (i) The...

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  19. Complete the follwing chemical equations for reactions : (i) Fe^(@+...

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  20. Explain the following observations: (i) Transition elements are know...

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