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Alkyl cyanides are .... soluble in water...

Alkyl cyanides are .... soluble in water than alkyl isocyanides.

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Why alkyl cyanides are soluble in water?

Explain : Alkyl cyanides are more soluble in water than corresponding alkyl isocyanides.

Alkyl cyanides generally have .... boiling points than isocyanides.

Why isocyanides are less soluble in water than the corresponding cyanides?

Alkyl iodides reacts with NaCN to form alkyl cyanides plus a little amount of alkyl isocyanides. The reason for the formation two types of products is-

Why are alkyl halides insoluble in water?

Explain : Treatment of alkyl halides with alcoholic KCN produces alkyl cyanides whereas with alc. AgCN produces alkyl isocyanides.

In the following questions, a statement of assertion (A) is following by a statement of reason (R ) A : when alkyl halide is reacted with AgCN then alkyl isocyanide is formed . R : AgCN is a covalent compound and only the site of nitrogen is available for the reaction.

In S_(N^1) reactions, primary alkyl halides are more reactive than tertiary alkyl halides.

Assertion : Alkyl isocyanides in acidified water give alkyl formamides. Reason : In isocyanides, carbon first act as a nucleophile and then as electrophile.

ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. According to IUPAC system, CH3 CH2 CN is named as ...... while CH3 CH2...

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  2. All isocyanides on hydrolysis with water in presence of HCI yield.....

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  3. Alkyl cyanides are .... soluble in water than alkyl isocyanides.

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  4. Alkyl isocyanides can be converted into cyanides by .....

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  5. Alkyl cyanides generally have .... boiling points than isocyanides.

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  6. Diphenylamine is less ........ than aniline.

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  7. Reaction of aniline with ......... yields C6 H5 N underset(to )= C a...

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  8. Benzenediazonium chloride is formed when ........ is treated with .......

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  9. Butane nitrile can be prepared by heating

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  10. Phenyl isocyanides are prepared by

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  11. The compound obtained by reducing CH3 CN with Na//C2 H5 OH is

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  12. An isonitrile on reduction gives

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  13. Hydrolysis of benzonitrile gives

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  14. Conversion of nitrobenzene to aniline is carried out in

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  15. Towards electrophilic substitution, the most reactive will be

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  16. Acetanilide is prepared by the reaction of acetyl chloride on

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  17. Which of the following gives carbylamine reaction?

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  18. The compound obtained by heating a mixture of a primary amine and chlo...

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  19. which of the following reactions will not give a primary amine ?

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  20. Gabrial synthesis is used for the preparation of

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