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Amongst the following, the strongest ba...

Amongst the following, the strongest base in aqueous medium is ______________ .

A

`CH_3 NH_2`

B

`NC CH_2 NH_2`

C

`(CH_3)_2 NH`

D

`C_6 H_5 NHCH_3`

Text Solution

Verified by Experts

The correct Answer is:
C

`(CH_3)_2 NH` being a `2^@` amine is more basic than `CH_3 NH_2 (1^@ ). NC C_2 NH_2` is less basic than `CH_3 NH_2` due to-I effect of CN group. `C_6 H_5 NHCH_3` is less basic than `CH_3 NH_2` as well as `(CH_3 )_2 NH` due to delocalization of lone pair of electrons on the N-atom into the benzene ring. Thus, `(CH_3)_2NH` is the strongest base.
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ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. Which of the following is a 3^@ amine?

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  2. The correct IUPAC name for CH2=CHCH2NHCH3 is

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  3. Amongst the following, the strongest base in aqueous medium is .

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  4. Which of the following is the weakest Bronsted base?

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  5. Benzyl amine may be alkylated as shown in the following equation : ...

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  6. Which of the following reagents would not be a good choice for reducin...

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  7. In order to prepare a 1^(@) amine from an alkyl halide with simultaneo...

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  8. The souce of nitrogen in Gabriel synthesis of amines is

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  9. Amongst the given set of reactants the most appropriate for preparing ...

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  10. The best reagent for converting 2-phenylpropanamide into 2-phenylpropa...

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  11. The best reagent for converting, 2-phenylpropanamide into 1-phenyletha...

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  12. Hofmann bromide degradation reaction is shown by

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  13. The correct increasing order of basic strength for the following compo...

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  14. Methylamine reacts with HNO2 to form

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  15. The gas evolved when methylamine reacts with nitrous acid is….

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  16. In the nitration of benzene using a mixture of conc. H2SO4 and conc. H...

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  17. Reduction of aromatic nitro compounds using Fe and HCl gives .

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  18. The most reactive amine towards dilute hydrochloric acid is .

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  19. Acid anhydrides on reaction with primary amine gives…

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  20. The reaction Aroverset(+)N(2)Cl^(-) overset(Cu//HCl)to ArCl +N(2) + ...

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