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Hofmann bromide degradation reaction is ...

Hofmann bromide degradation reaction is shown by

A

`ArNH_2`

B

`ArCONH_2`

C

`ArNO_2`

D

`ArCH_2 NH_2`

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The correct Answer is:
To solve the question regarding which compound undergoes the Hofmann bromide degradation reaction, we can follow these steps: ### Step 1: Understand the Hofmann Bromide Degradation Reaction The Hofmann bromide degradation reaction involves the conversion of an amide into a primary amine in the presence of bromine (Br2) and sodium hydroxide (NaOH). The general reaction can be represented as follows: \[ \text{R-C(=O)-NH}_2 + \text{Br}_2 + \text{NaOH} \rightarrow \text{R-NH}_2 + \text{byproducts} \] ### Step 2: Identify the Structure of Amides Amides have the general structure of R-C(=O)-NH2, where R is an alkyl or aryl group. This structure is essential for the Hofmann degradation to occur. ### Step 3: Analyze the Given Options We need to analyze the options provided in the question to determine which one represents an amide that can undergo Hofmann bromide degradation. 1. **Option A:** R-NH2 (This is a primary amine, not an amide) 2. **Option B:** R-C(=O)-NH2 (This is the structure of an amide) 3. **Option C:** R-C(=O)-R' (This is a ketone, not an amide) 4. **Option D:** R-C(=O)-R'' (This is also a ketone, not an amide) ### Step 4: Select the Correct Option From the analysis, we see that only **Option B (R-C(=O)-NH2)** is an amide that can undergo Hofmann bromide degradation. Thus, the correct answer is **Option B**. ### Summary of the Solution: The Hofmann bromide degradation reaction is shown by amides, specifically represented by the structure R-C(=O)-NH2. Among the given options, only Option B fits this criterion. ---

To solve the question regarding which compound undergoes the Hofmann bromide degradation reaction, we can follow these steps: ### Step 1: Understand the Hofmann Bromide Degradation Reaction The Hofmann bromide degradation reaction involves the conversion of an amide into a primary amine in the presence of bromine (Br2) and sodium hydroxide (NaOH). The general reaction can be represented as follows: \[ \text{R-C(=O)-NH}_2 + \text{Br}_2 + \text{NaOH} \rightarrow \text{R-NH}_2 + \text{byproducts} \] ### Step 2: Identify the Structure of Amides ...
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ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-I OBJECTIVE QUESTIONS)
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  9. The most reactive amine towards dilute hydrochloric acid is .

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  17. Which of the following should be most volatile ?

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