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The correct decreasing order of basic st...

The correct decreasing order of basic strength of the following species is ….. `H_(2)O, NH_(3), OH^(-),NH_(2)^(-)`

A

`NH_(2)^(-) gt OH^(-) gt NH_3 gt H_2 O`

B

`OH^(-) gt NH_(2)^(-) gt H_2 O gt NH_3`

C

`NH_(3) gt H_2 O gt NH_(2)^(-) gt OH^(-)`

D

`H_(2) O gt NH_(3) gt OH^(-) gt NH_(2)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

`H_2 O` is a stronger acid than `NH_3` or `NH_3` is more basic than water. Conjugate base of weaker acid `NH_3`, i.e., `NH_(2)^(-)` is a stronger base than the conjugate base of stronger acid `(H_2 O)` i.e, `OH^(-)`.
Hence, the order of basic strength is `NH_(2)^(-) gt OH^(-) gt NH_3 gt H_2 O`
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ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-I OBJECTIVE QUESTIONS)
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  2. Among the following amines, the strongest Bronsted base is….

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  4. Which of the following should be most volatile ?

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  5. Which of the following methods of preparation of amines will not give ...

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  7. Nitrosoamines are formed byunderline(" primary amines").

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  8. Pure primary amines underline("can be prepared ")by the action of ammo...

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  9. Amides on treatment with Br2 and KOH form the amines having the underl...

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  10. There are three underline ("position isomers ")of the amine having mol...

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  11. Trimethylamine is less basic than dimethylamine.

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  12. Ethanamine reacts with benzenesulfonyl chloride to form N-ethylbenzene...

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  13. The treatment of an alkyl halide with underline("silver cyanide ")form...

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  14. The hydrolysis of an underline ("alkyl cyanide ")always yields formic ...

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  15. Carbylamine reaction is given by underline ("secondary amines").

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  16. Alkyl cyanides areunderline(" as poisonous as KCN").

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  17. Alkyl cyanides have underline("lower ")boiling points than the isomeri...

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  18. Catalytic reduction of isocyanides givesunderline(" primary amines").

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  19. Reduction of nitrobenzene with H2 in presence of platinum gives under...

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  20. Aniline is a weaker base than benzyl amine.

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