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Arrange the following in increasing orde...

Arrange the following in increasing order of basic strength:
Aniline,p-Nitroaniline and p-toluidine

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p-nitroaniline `lt` Aniline `lt` p-Toluidine
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(a) Account for the following : (i) Direct nitration of aniline yields significant amount of meta derivative. (ii) Primary aromatic cannot be prepared by Gabriel phthalimide synthesis. (b) Carry out the following conversions : (i) Ethanoic acid into methanamine. (ii) Aniline to p-Bromoniline. (c) Arrange the following in increasing order of basic strength : Aniline, p-nitroaniline and p-toludine.

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Correct order of basic strength is :

Arrange the following in decreasing order of their basic strength: ammonia, triethylamine, aniline, ethylamine and diethylamine.

ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-II DESCRIPTIVE QUESTIONS- SHORT ANSWER QUESTIONS )
  1. Explain the following: Aniline is a weaker base than ethylamine.

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  2. Arrange the following sets in order of their basic strength: Ethyla...

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  3. Arrange the following in increasing order of basic strength: Aniline...

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  4. Aniline is a weaker base than benzyl amine.

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  5. Why is aniline soluble in aqueous HCl?

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  6. Explain the following: Aniline readily reacts with bromine to give ...

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  7. How will you convert aniline into: (i) benzonitrile (i) acetanilide (i...

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  8. Which amine in each of the following pairs is a stronger base? Give re...

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  9. Which amine in each of the following pairs is a stronger base? Give re...

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  10. Give the IUPAC names of the following: CH3 NC

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  11. Give the IUPAC names of the following:

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  12. Give the IUPAC names of the following:

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  13. Give the IUPAC names of the following: CH3 CH ( Br ) CH2 CN

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  14. How would you prepare alkyl cyanides from: Primary amines

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  15. How would you prepare alkyl cyanides from: Alkyl halides

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  16. How would you prepare alkyl cyanides from: acid amides?

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  17. What are ambident nucleophiles ? Example with an example.

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  18. Haloalkanes react with KCN to form alkyl cyanides as main product whil...

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  19. How will you prepare alkyl isocyanides from: Primary amines

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  20. How will you prepare alkyl isocyanides from: Alkyl halides?

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