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Account for the following: Tertiary am...

Account for the following:
Tertiary amines do not undergo acylation reaction

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To account for why tertiary amines do not undergo acylation reactions, we can break down the explanation into several steps: ### Step 1: Understand the Structure of Tertiary Amines Tertiary amines have the general structure R3N, where R represents alkyl or aryl groups. In this structure, the nitrogen atom is bonded to three carbon-containing groups and does not have any hydrogen atoms attached to it. ### Step 2: Define Acylation Reaction Acylation is a reaction where an acyl group (RCO-) is introduced into a compound. For amines, this typically involves the reaction of the amine with an acyl chloride or an anhydride, resulting in the formation of an amide. ...
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ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-II DESCRIPTIVE QUESTIONS- LONG ANSWER QUESTIONS )
  1. How will you convert: a carboxylic acid to a primary amine having on...

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  2. Account for the following: Amines are basic while amides are neutr...

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  3. Account for the following: Tertiary amines do not undergo acylation ...

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  4. Trimethylamine is less basic than dimethylamine.

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  5. Electrophilic substitution in case of aromatic amines takes place more...

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  6. Account for the following: Alkylamines are stronger bases than aryl...

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  7. Account for the following: Aniline is acylated first to prepare its...

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  8. How is aniline prepared on a large scale ?

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  9. What happens when aniline is heated with a mixture of conc. nitric...

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  10. Electrophilic substitution of aniline with bromine water at room tempe...

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  11. When aniline is heated with conc. H2SO4 at 455-475 K, it forms

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  12. How will you distinguish between primary, secondary and tertiary amine...

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  13. Give three points of distinction between ethylamine and aniline.

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  14. How is aniline diazotised ? Write chemical reactions.

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  15. How will you canvert the following : (i) Nitrobenzene into aniline, ...

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  16. How is m-nitroaniline obtained from nitrobenzene?

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  17. Bring out the following conversions : Aniline to phenyl isocyanide.

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  18. How will you bring about the following conversions ? Ethylamine to...

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  19. How will you bring about the following conversions ? Aniline to br...

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  20. How will you bring about the following conversions ? Aniline to su...

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