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Electrophilic substitution in case of ar...

Electrophilic substitution in case of aromatic amines takes place more readily than in benzene.

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To reduce the activating effect of `NH_2` group.
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Electrophilic aromatic substitution is difficult in

Electrophilic substitution in benzoic acid takes place at meta position why ?

Electrophilic subsitution reaction in phenol take place at :

Nitration is an example of aromatic electrophilic substitution and its rate depends upon the group already present in the benzene ring. Out of benzene and phenol, which one is more easily nitrated and why ?

Explain why are electrophilic substitution reactions the most characteristic reactions of benzene?

(a) How will you convert (i) Benzene to acetophenone (ii) Propanone to 2-Methylpropan-2-ol (b) Give reasons : (i) Electrophilic substitution in benzoic acid takes place at meta position. (ii) Carboxlic acids are higher boiling liquids than aldehydes,, ketones and alchols of comparable molecular masses. (iii) Propanal is more reactive than propanone in nucleophilic addition reactions.

For an electrophilic substitution reaction , the presence of a halogen atom in the benzene ring …..

A : Aromatic aldehydes are less reactive than aliphatic aldehyde towards nucleophilic substitution reaction. R : In case of aromatic aldehyde,+R effect of phenyl ring is present.

The substitution will mainly take place at position :

ICSE-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE (PART-II DESCRIPTIVE QUESTIONS- LONG ANSWER QUESTIONS )
  1. Account for the following: Tertiary amines do not undergo acylation ...

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  2. Trimethylamine is less basic than dimethylamine.

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  3. Electrophilic substitution in case of aromatic amines takes place more...

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  4. Account for the following: Alkylamines are stronger bases than aryl...

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  5. Account for the following: Aniline is acylated first to prepare its...

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  6. How is aniline prepared on a large scale ?

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  7. What happens when aniline is heated with a mixture of conc. nitric...

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  8. Electrophilic substitution of aniline with bromine water at room tempe...

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  9. When aniline is heated with conc. H2SO4 at 455-475 K, it forms

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  10. How will you distinguish between primary, secondary and tertiary amine...

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  11. Give three points of distinction between ethylamine and aniline.

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  12. How is aniline diazotised ? Write chemical reactions.

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  13. How will you canvert the following : (i) Nitrobenzene into aniline, ...

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  14. How is m-nitroaniline obtained from nitrobenzene?

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  15. Bring out the following conversions : Aniline to phenyl isocyanide.

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  16. How will you bring about the following conversions ? Ethylamine to...

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  17. How will you bring about the following conversions ? Aniline to br...

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  18. How will you bring about the following conversions ? Aniline to su...

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  19. How will you bring about the following conversions ? Aniline to o-...

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  20. How will you bring about the following conversions ? C6 H5 N2 Cl...

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