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40 mg of pure NaOH is dissolved in 10 l...

40 mg of pure NaOH is dissolved in 10 litres of distilled water. The pH of the solution is

A

`9 `

B

` 10 `

C

` 11`

D

`12`

Text Solution

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The correct Answer is:
To find the pH of a solution made by dissolving 40 mg of pure NaOH in 10 liters of distilled water, we can follow these steps: ### Step 1: Convert the mass of NaOH to grams Given: - Mass of NaOH = 40 mg To convert milligrams to grams: \[ \text{Mass in grams} = \frac{40 \text{ mg}}{1000} = 0.040 \text{ g} \] ### Step 2: Calculate the number of moles of NaOH The molar mass of NaOH is approximately 40 g/mol. Using the formula: \[ \text{Moles of NaOH} = \frac{\text{mass in grams}}{\text{molar mass in g/mol}} \] Substituting the values: \[ \text{Moles of NaOH} = \frac{0.040 \text{ g}}{40 \text{ g/mol}} = 0.001 \text{ moles} \] ### Step 3: Calculate the concentration of NaOH in the solution The volume of the solution is given as 10 liters. Using the formula for concentration: \[ \text{Concentration (M)} = \frac{\text{moles}}{\text{volume in liters}} \] Substituting the values: \[ \text{Concentration of NaOH} = \frac{0.001 \text{ moles}}{10 \text{ L}} = 0.0001 \text{ M} = 10^{-4} \text{ M} \] ### Step 4: Calculate the pOH of the solution Since NaOH is a strong base, it dissociates completely in water: \[ \text{NaOH} \rightarrow \text{Na}^+ + \text{OH}^- \] Thus, the concentration of OH⁻ ions is also \(10^{-4} \text{ M}\). Using the formula for pOH: \[ \text{pOH} = -\log[\text{OH}^-] \] Substituting the concentration: \[ \text{pOH} = -\log(10^{-4}) = 4 \] ### Step 5: Calculate the pH of the solution We know the relationship between pH and pOH: \[ \text{pH} + \text{pOH} = 14 \] Substituting the value of pOH: \[ \text{pH} + 4 = 14 \] Thus, \[ \text{pH} = 14 - 4 = 10 \] ### Final Answer The pH of the solution is **10**. ---
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