Home
Class 11
CHEMISTRY
Which one of the following conditions wi...

Which one of the following conditions will favour maximum formation of the product in the reaction.
` A_2(g) +B_2(g) hArr X_2(g) , Delta rH =-XkJ ? `

A

low temperature and high pressure

B

Low temperature and low pressure

C

High temperature and high pressure

D

High temperature and low pressure.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the conditions that will favor the maximum formation of the product in the reaction \( A_2(g) + B_2(g) \rightleftharpoons X_2(g) \) with \( \Delta_rH = -X \, \text{kJ} \), we will analyze the effects of temperature and pressure based on Le Chatelier's principle. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: The reaction is given as: \[ A_2(g) + B_2(g) \rightleftharpoons X_2(g) \] The enthalpy change \( \Delta_rH \) is negative, indicating that the reaction is exothermic (it releases heat). **Hint**: Remember that a negative \( \Delta H \) indicates an exothermic reaction. 2. **Analyze the Effect of Pressure**: - Count the number of moles of gas on each side of the reaction: - Reactants: \( A_2 + B_2 \) = 2 moles - Products: \( X_2 \) = 1 mole - According to Le Chatelier's principle, increasing the pressure will favor the side with fewer moles of gas. Since the product side has fewer moles (1 mole) compared to the reactant side (2 moles), increasing the pressure will favor the formation of \( X_2 \). **Hint**: Increasing pressure shifts the equilibrium toward the side with fewer gas moles. 3. **Analyze the Effect of Temperature**: - For exothermic reactions, lowering the temperature favors the formation of products. Since our reaction is exothermic, a low temperature will favor the forward reaction (formation of \( X_2 \)). - Conversely, increasing the temperature would favor the reverse reaction (formation of reactants). **Hint**: For exothermic reactions, lower temperatures favor product formation. 4. **Combine the Findings**: - From the analysis, we conclude that to maximize the formation of the product \( X_2 \): - **High Pressure** is needed to favor the side with fewer moles. - **Low Temperature** is needed to favor the exothermic reaction. 5. **Select the Correct Option**: - The conditions that favor maximum formation of the product are **high pressure and low temperature**. ### Final Answer: The conditions that will favor maximum formation of the product \( X_2 \) are **high pressure and low temperature**.
Promotional Banner

Topper's Solved these Questions

  • EQUILIBRIUM

    ICSE|Exercise TRUE OR FALSE TYPE QUESTION |22 Videos
  • EQUILIBRIUM

    ICSE|Exercise FILL IN THE BLANKS TYPE QUESTIONS |34 Videos
  • EQUILIBRIUM

    ICSE|Exercise ESSAY (LONG ANSWER) TYPE QUESTIONS |17 Videos
  • ENVIRONMENTAL CHEMISTRY

    ICSE|Exercise NCERT TEXT-BOOK EXERCISE|20 Videos
  • HYDROCARBONS

    ICSE|Exercise NCERT TEXT-BOOK EXERCISES |46 Videos

Similar Questions

Explore conceptually related problems

In the reactions H_2(g) +Cl_2 ( g) hArr 2HCl (g) .

For the reaction N_(2)(g) + 3H_(2)(g) hArr 2NH_(3)(g), DeltaH=?

For the reaction, N_2[g] + 3H_2[g] hArr 2NH_3[g] , Delta H = …

In the reaction 2H_(2)(g) + O_(2)(g) rarr 2H_(2)O (l), " "Delta H = - xkJ

The yield of product in the reaction 2A_((g)) + B_((g)) hArr 2C_((g)) + Q K J would be lower at :

In the reaction: 2CO(g) +O_(2)(g) hArr 2CO(g) , entropy decreases.

Discuss the conditions for obtaining the maximum yield in the following reactions. N_2(g) + 3H_2(g) hArr 2NH_3(g) , " " Delta H = - 43. 2 kcal

The yield of product in the reaction, A_(2)(g)+2B(g) hArr C(g)+Q KJ would be higher at:

The K_c for given reaction will be A_2 (g) +2B (g) hArr C(g) +2D(s)

In which of the following reactions, the formation of product is favoured by decrease in temperature ? (1) N_(2)(g)+O_(2)(g)hArr2NO(g), DeltaH^(@)=181 (2) 2CO_(2)(g)hArr2CO(g)+O_(2)(g), DeltaH^(@)=566 (3) H_(2)(g)+I_(2)hArr2HI(g), DeltaH^(@)=-9.4 (4) H_(2)(g)+F_(2)(g)hArr2HF(g),DeltaH^(@)=-541

ICSE-EQUILIBRIUM -OBJECTIVE (MULTIPLE CHOICE ) TYPE QUESTIONS
  1. A 20 litre container at 400 K contains CO2(g) at pressure 0.4 atm a...

    Text Solution

    |

  2. The equilibrium constant of the following are : " ...

    Text Solution

    |

  3. pK(a) of a weak acid (HA) and pK(b) of a weak base (BOH) are 3.2 and 3...

    Text Solution

    |

  4. The solubility of BaSO4 in water is 2.42 xx 10^(-3) gL^(-1) at 298 ...

    Text Solution

    |

  5. Which one of the following conditions will favour maximum formation o...

    Text Solution

    |

  6. Following solutions were prepared by mixing different volumes of NaOH ...

    Text Solution

    |

  7. An aqueous solution contains 0.10 MH2 S and 0.20 M HCl if the equil...

    Text Solution

    |

  8. An aqueous solution contains an unknown concentration Ba^(2+) . Wh...

    Text Solution

    |

  9. Which of the following are Lewis acids?

    Text Solution

    |

  10. Which of the following salts is the most basic in aqueous solution? ...

    Text Solution

    |

  11. An alkali is titrated against an acid with methyl orange as indicato...

    Text Solution

    |

  12. pH of a saturated solution of Ca(OH)2 is 9. The solubility product (...

    Text Solution

    |

  13. Conjugate base the Bronsted acids H2O and HF are :

    Text Solution

    |

  14. Which will make basic buffer? a) 100 m L o f 0.1 M HCl + 200 m...

    Text Solution

    |

  15. Solubility of Cd(OH)(2) in pure water is 1.84xx10^(-5)"mole"//L Calcul...

    Text Solution

    |

  16. In which one of the following equilibrium , Kp ne Kc ?

    Text Solution

    |

  17. In an acid- base titration, 0.1 M HCl solution was added to the NaO...

    Text Solution

    |

  18. If solubility product of Zr(3)(PO(4))(4) is denoted by S, then which o...

    Text Solution

    |

  19. For the solution of the gases w,x,y and z in water at 298 K the Henry'...

    Text Solution

    |

  20. S(s)+O(2)hArrSO(2)(g)" "K(1)=10^(52) 2S(s)+3O(2)hArr2SO(3)(g)" "...

    Text Solution

    |