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If equilibrium constant for the reactio...

If equilibrium constant for the reactions.
` A_2 +B_2 hArr 2AB,`
is K , then the backward reactions.
` AB hArr (1)/(2) A_2 + (1)/(2) B_2.`
its value is 1/K . Is it true or false? If false then write the correct constant.

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The correct Answer is:
To solve the problem, we need to analyze the equilibrium constants for the given reactions step by step. ### Step 1: Identify the Forward Reaction and its Equilibrium Constant The forward reaction is given as: \[ A_2 + B_2 \rightleftharpoons 2AB \] The equilibrium constant \( K \) for this reaction can be expressed as: \[ K = \frac{[AB]^2}{[A_2][B_2]} \] ### Step 2: Write the Backward Reaction The backward reaction is: \[ 2AB \rightleftharpoons A_2 + B_2 \] For this reaction, the equilibrium constant \( K' \) can be expressed as: \[ K' = \frac{[A_2][B_2]}{[AB]^2} \] ### Step 3: Relate the Backward Reaction to the Forward Reaction From the relationship of equilibrium constants for forward and backward reactions, we know: \[ K' = \frac{1}{K} \] ### Step 4: Consider the Reaction with Coefficients Now, we need to consider the reaction: \[ AB \rightleftharpoons \frac{1}{2} A_2 + \frac{1}{2} B_2 \] This reaction is obtained by dividing the backward reaction by 2. When we divide the coefficients of a balanced equation by a factor, the equilibrium constant changes according to the power of that factor. ### Step 5: Calculate the New Equilibrium Constant When we divide the entire reaction by 2, the new equilibrium constant \( K'' \) is given by: \[ K'' = K'^{1/2} \] Substituting \( K' = \frac{1}{K} \): \[ K'' = \left(\frac{1}{K}\right)^{1/2} = \frac{1}{\sqrt{K}} \] ### Conclusion The statement in the question is **false**. The correct equilibrium constant for the reaction \( AB \rightleftharpoons \frac{1}{2} A_2 + \frac{1}{2} B_2 \) is: \[ K'' = \frac{1}{\sqrt{K}} \]
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