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In the group II of qualitative analysis...

In the group II of qualitative analysis, It is necessary to pass `H_2S ` in …………. Medium , otherwise the sulphides of the cations of group ……… will also get precipitated.

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To solve the question, we need to understand the context of qualitative analysis in chemistry, specifically regarding the precipitation of sulfides when passing hydrogen sulfide (H₂S) gas. ### Step-by-Step Solution: 1. **Understanding the Groups in Qualitative Analysis**: - In qualitative analysis, cations are divided into different groups based on their solubility and the reagents used for their identification. Group II cations typically include those that form insoluble sulfides when H₂S is introduced. 2. **Identifying the Medium**: ...
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In equalitative analysis, cations of graph II as well as group IV both are precipitated in the form of sulphides. Due to low value of K_(sp) of group II sulphides, group reagent is H_(2)S in the presence of dil. HC1 , and due to high value of K_(sp) of group IV sulphides, group reagent is H_(2)S in the presence of NH_(4)OH and NH_(4)C1 . In a solution containing 0.1M each of Sn^(2+), Cd^(2+) , and Ni^(2+) ions, H_(2)S gas is passed. K_(sp) of SnS = 8 xx 10^(-29), K_(sp) of CdS = 15 10^(-28), K_(sp) of NiS - 3 xx 10^(-21), K_(1) of H_(2)S = 1 xx 10^(-7), K_(2) of H_(2)S = 1 xx 10^(-14) If H_(2)S is passed into the above mixture in the presence of HC1 , which ion will be precipitated first?

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