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A dihaloalkane (A), C2 H8 Cl2 on reactio...

A dihaloalkane (A), `C_2 H_8 Cl_2` on reaction with alc. KOH gives (B), `C_6 H_6.` (B) does not form white precipitate with ammonical silver nitrate and on hydrogenation absorbs two moles of hydrogen to give n-butane. Compound (B) reacts with two molecules of ozone to form a diozonide which on reductive hydrolysis gives two moles of formaldehyde and one mole of glyoxal. Identify (A) and (B) and explain the reactions.

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To solve the problem, we need to identify the compounds (A) and (B) based on the given information and reactions. Let's break it down step by step. ### Step 1: Identify Compound A The molecular formula for compound A is given as `C2H8Cl2`. This indicates that it is a dihaloalkane. - The presence of two chlorine atoms suggests that it can be a 1,4-dichlorobutane, which can be represented as: \[ \text{CH}_2\text{Cl}-\text{CH}_2-\text{CH}_2-\text{CH}_2\text{Cl} ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -REVIEW EXERCISES
  1. A primary alcohol (A) with V.D. = 29 contains C = 62.1%, H = 10.3%. It...

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  2. A compound (X) having molecular formula C6 H(10) gave 2-methylpentane ...

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  3. A dihaloalkane (A), C2 H8 Cl2 on reaction with alc. KOH gives (B), C6 ...

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  4. Establish the structure of a hydrocarbon C5 H(10) from the following ...

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  5. A hydrocarbon (V.D. = 27) containing C = 88.88% decolourised KMnO4 sol...

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  6. An organic compound (A) having V.D. = 30 contains C = 60.0% and H= 13%...

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  7. An organic compound E (C5 H8) on hydrogenation gives compound F (C5 H(...

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  8. An aliphatic hydrocarbon (A) of molecular weight 58 yields on chlorina...

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  9. Arrange the following in the order as mentioned : (CH3)3 C-(CH3)2 CH...

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  10. Arrange the following in the order as mentioned : -CN, -CI, -OH, -NO2...

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  11. Arrange the following in the order as mentioned : overset(+ )CH3 CH3 ...

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  12. Arrange the following in the order as mentioned : 1^@ , 2^@ , 3^@ f...

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  13. What are the main points of difference between inductive and electrome...

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  14. Explain the l-effect leads to the development of partial charges ...

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  15. Explain the Hyperconjugation effect is also termed as 'no bond reso...

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  16. Explain the overset(* )CH3 is more reactive than CH3 CH2 free radic...

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  17. Explain the The carbanions are very reactive species although their...

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  18. Explain the BF3 acts as an electrophile.

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  19. Explain the CH3 NH2 acts as a nucleophile.

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  20. Why is in the presence of diethyl peroxide, the addition of HBr to pro...

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