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Explain the overset(* )CH3 is more re...

Explain the
`overset(* )CH_3` is more reactive than `CH_3 CH_2` free radical.

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Explain why (CH_(3))_(3)overset(+)C is more stable than CH_(3)overset(+)CH_(2) and CH_(3) is the least stable cation

Explain the following : (a) Why MeNH overset (oplus) CH_2 (I) is more stable more than MeCH_2 overset (oplus) CH_2 (II) when both are 1^@ carbocations ? (b) Which of the following intermediate is unstable ? ( c) Why allylic free radical (CH_2 - CH = CH_2) (I) is more stable than propy1 free radical (dot C H_2 - CH_2 - CH_3) (II) , when both are 1^@ free radicals ?

Arrange the following in the order as mentioned : overset(+ )CH_3 CH_3 overset(+)CH_2, (CH_3)_2 CHoverset(+), (CH_3)_3 + C carbocations in the order of increasing reactivity,

Write the IUPAC names of the following compounds : CH_3 - overset(CH_3) overset(|) CH - CH_2 - CH_2 - overset(O ) overset( ||)C-CH_2 Cl

Explain the mechanism of the reaction is given below : 2CH_3-CH_2-OHunderset(413K)overset(H^+)to CH_3CH_2-O-CH_2-CH_3+H_2O

Which one of the following compounds is more reactive towards S_(N)2 reaction and why ? CH_3CH(Cl) CH_2CH_3 or CH_3CH_2CH_2Cl

A: CH_(3)-CH-CH_(3) has 6. hyperconjugative hydrogens while CH_(3)-CH-CH_(2) -CH_(3) has 5 hyperconjugative hydrogens. R: CH_(3)-CH-CH_(3) is more stable than CH_(3)-CH-CH_(2)- CH_3

In iso-pentane, the H atom that can be most easily substituated by free radical mechanism is on:- overset(1)CH_(3)-underset(CH_(3))underset(|)overset(2)CH-overset(3)CH_(2)overset(4)CH_(3)

ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -REVIEW EXERCISES
  1. Establish the structure of a hydrocarbon C5 H(10) from the following ...

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  2. A hydrocarbon (V.D. = 27) containing C = 88.88% decolourised KMnO4 sol...

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  3. An organic compound (A) having V.D. = 30 contains C = 60.0% and H= 13%...

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  4. An organic compound E (C5 H8) on hydrogenation gives compound F (C5 H(...

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  5. An aliphatic hydrocarbon (A) of molecular weight 58 yields on chlorina...

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  6. Arrange the following in the order as mentioned : (CH3)3 C-(CH3)2 CH...

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  7. Arrange the following in the order as mentioned : -CN, -CI, -OH, -NO2...

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  8. Arrange the following in the order as mentioned : overset(+ )CH3 CH3 ...

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  9. Arrange the following in the order as mentioned : 1^@ , 2^@ , 3^@ f...

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  10. What are the main points of difference between inductive and electrome...

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  11. Explain the l-effect leads to the development of partial charges ...

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  12. Explain the Hyperconjugation effect is also termed as 'no bond reso...

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  13. Explain the overset(* )CH3 is more reactive than CH3 CH2 free radic...

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  14. Explain the The carbanions are very reactive species although their...

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  15. Explain the BF3 acts as an electrophile.

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  16. Explain the CH3 NH2 acts as a nucleophile.

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  17. Why is in the presence of diethyl peroxide, the addition of HBr to pro...

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  18. Why is chloroacetic acid is a stronger acid as compared to acetic acid...

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  19. Explain the (CH3)3 C^(-) is less stable than bar(C) H3.

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  20. Explain the A singlet carbene has a bent structure.

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