Why is in the presence of diethyl peroxi...

Why is in the presence of diethyl peroxide, the addition of HBr to propene is against Markownikoff's rule?

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In the presence of peroxide addition of HBr to propene takes place according to anti Markownikoff's rule but peroxide effect is not seen in the case of HCl and HI. Explain.

The intermediate formed in the electrophilic addition of HBr to propene is a

Assertion: -The addition of HCl to unsymmetrical alkenes in the presence of organic peroxides takes place against Markownikoff's rule. Reason :- 2^@ free radicals are more stable than 1^@ free radicals.

Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same reaction yields 1-bromopropane. Explain and give mechanism.

A) Addition of HBr on 2-butene gives two isomeric products. R) Addition of HBr on 2-butene follows Markownikoff's rule.

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The intermediate during the addition of HCl to propene in the presence of peroxide is :

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