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Why is dichloroacetic acid stronger than...

Why is dichloroacetic acid stronger than monochloroacetic acid ?

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To understand why dichloroacetic acid is stronger than monochloroacetic acid, we need to analyze the structures and the stability of their conjugate bases. Here’s a step-by-step breakdown of the explanation: ### Step 1: Draw the Structures - **Dichloroacetic Acid**: This acid has two chlorine atoms attached to the acetic acid structure. - **Monochloroacetic Acid**: This acid has one chlorine atom attached to the acetic acid structure. ### Step 2: Remove the Acetic Hydrogen - When we consider the acidic nature of these compounds, we need to remove the acidic hydrogen (the hydrogen atom attached to the carboxylic group, -COOH) to form their conjugate bases. ...
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ICSE-ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES AND TECHNIQUES -SHORT ANSWER TYPE QUESTIONS
  1. How is + l-effect different from - l-effect? Illustrate with examples.

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  2. Why is +l-effect of t-butyl group greater than that of isopropyl group...

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  3. Why is dichloroacetic acid stronger than monochloroacetic acid ?

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  4. Define electromeric effect.

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  5. What type of effects are involved in the following reactions ?

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  6. What are the main points of difference between inductive and electrome...

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  7. When does mesomeric effect come into existence ? Illustrate with examp...

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  8. Define mesomeric effect and differentiate + M-effect from - M-effect.

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  9. Compare inductive effect with mesomeric effect.

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  10. What do you understand by hyperconjugation effect ? Illustrate with an...

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  11. Explain the Hyperconjugation effect is also termed as 'no bond reso...

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  12. Why is the hyperconjugation effect exerted by a methyl group greater t...

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  13. Define heterolytic fission of a covalent bond.

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  14. Why is a 3^@ radical more stable as compared to 1^@ and 2^@ free r...

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  15. What are carbocations ? Give two examples.

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  16. Discuss the orbital structure of a carbocation.

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  17. What is relative order of reactivity of various types of carbocations ...

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  18. Define carbanion and discuss its orbital structure.

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  19. Why is 1^@ carbanion more stable than a 2 carbanion ?

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  20. What are carbenes ?

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